首页> 外文期刊>International Journal of Electrochemical Science >Macroporous Silicon Formation on Low-resistivity p-type c-Si Substrate by Metal-catalyzed Electrochemical Etching
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Macroporous Silicon Formation on Low-resistivity p-type c-Si Substrate by Metal-catalyzed Electrochemical Etching

机译:金属催化电化学刻蚀在低电阻率p型c-Si衬底上形成大孔硅

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Macroporous silicon with large aperture size was fabricated on p-type c-Si substrate with the resistivityof about 0.1-3 ohmcm by metalatalyzed electrochemical etching (MCECE). Firstly, Agnanoparticle catalyst was fabricated on c-Si by immersing the substrate into an aqueous solution of HFand AgNO3. Electrochemical etching was then performed in a HF-H2O2 solution. The synergetic effectof the Ag catalyst and the external applied electric field successfully facilitated the formation ofmacroporous silicon with large aperture size, which could not be obtained by single metalatalyzedelectroless etching (MCEE) or electrochemical etching (ECE). An etching model was proposed toillustrate the MCECE mechanism.
机译:通过金属催化电化学刻蚀(MCECE),在电阻率约为0.1-3 ohmcm的p型c-Si衬底上制备了大孔径大孔硅。首先,通过将衬底浸入HF和AgNO3的水溶液中,在c-Si上制备Agnanoparticle催化剂。然后在HF-H2O2溶液中进行电化学蚀刻。 Ag催化剂与外加电场的协同作用成功地促进了大孔径硅的形成,这是单金属催化化学蚀刻(MCEE)或电化学蚀刻(ECE)无法实现的。提出了刻蚀模型来说明MCECE机制。

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