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Thermodynamics of the System of Distinguishable Particles

机译:可区分粒子系统的热力学

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The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the entropy is not extensive. The inextensivity leads to the so-called Gibbs paradox in which the mixing entropy of two identical classical gases increases. Lots of literature from different points of view were created to resolve the paradox. In this paper, starting from the Boltzmann entropy, we present the thermodynamics of the system of distinguishable particles. A straightforward way to get the corrected Boltzmann counting is shown. The corrected Boltzmann counting factor can be justified in classical statistical mechanics.
机译:本文讨论了可区分颗粒系统的热力学问题。从玻耳兹曼熵的定义构造可区分粒子的统计力学时,发现熵并不广泛。这种不张性导致了所谓的吉布斯悖论,其中两种相同的经典气体的混合熵增加了。为了解决这一矛盾,从不同角度提出了许多文献。本文从玻尔兹曼熵开始,介绍了可分辨颗粒系统的热力学。显示了获得校正的玻尔兹曼计数的直接方法。校正后的玻尔兹曼计数因子可以在经典统计力学中证明。

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