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Binding of volatile aroma compounds to can linings with different polymeric characteristics

机译:挥发性香气化合物与具有不同聚合特性的罐衬的结合

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Flavor compounds have been shown to interact with packaging materials either by scalping, the movement of flavorings from the food product to the package, or by flavor release, movement of flavorings from the package to the food. Work has elucidated the parameters important for the scalping of flavor compounds to polyolefin packaging materials, but very little work has been conducted examining the scalping of flavor compounds by can lining materials. Can linings composed of three different polymers, polyolefin, acrylic, epoxy, were studied for binding of volatile flavor compounds (octanal, nonanal, decanal, eugenol, d ‐limonene) at room temperature over a 2‐week period. Solid phase microextraction (SPME) was used with gas chromatography mass spectrometry to identify and quantify volatile compounds. Flavor compounds were studied at concentrations around 4–1,000?ppb. Fourier transform infrared spectroscopy was used to verify can lining polymer chemistry. Almost complete binding of all five of the volatile compounds studied was observed over 9–14?days at room temperature for each of the can lining chemistries. The number of time data points limited our ability to determine the order and rate constants of binding. This model system appears to be a valuable for investigating flavor binding of polymeric can lining materials.
机译:已经显示调味料化合物通过剥头皮,调味料从食品到包装的移动或通过调味剂释放,调味料从包装到食品的移动与包装材料相互作用。工作已经阐明了对于将香料化合物剥皮到聚烯烃包装材料上的剥皮很重要的参数,但是很少进行检查罐头衬里材料对香料化合物剥皮的工作。研究了由三种不同聚合物(聚烯烃,丙烯酸,环氧)组成的罐衬在室温下在两周内对挥发性风味化合物(辛醛,壬醛,癸醛,丁子香酚,d-柠檬烯)的粘合性。固相微萃取(SPME)与气相色谱质谱联用,以鉴定和定量挥发性化合物。研究了风味化合物的浓度约为4–1,000?ppb。傅里叶变换红外光谱用于验证罐衬聚合物化学。在室温下,对于每种罐头衬里化学品,在9–14天内观察到所研究的所有五种挥发性化合物几乎完全结合。时间数据点的数量限制了我们确定绑定顺序和速率常数的能力。该模型系统对于研究聚合物罐内衬材料的风味结合似乎很有价值。

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