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Production of Fe3-xZnxO4 Nanoparticles for Agents in Hyperthermia Treatment

机译:Fe3-xZnxO4纳米粒子的制备,用于热疗药物

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Fe3-xZnxO4 (x=0.2, 0.4, 0.6, 0.8, 1) nanoparticle with average diameters of 12 nm was produced by our novel wet chemical method. The crystal structure and magnetic property of the obtained particle were investigated by X-ray diffraction and superconducting quantum interference device (SQUID) magnetometer. Direct current (DC) magnetization measurement showed that the coercive force Hc and saturation magnetization Ms decreased as the composite parameter x increased. This phenomenon suggests that Zn2+ ions located on tetrahedral A sites weaken the superexchange interaction between tetrahedral A and octahedral B sites. From the alternative current (AC) magnetic susceptibility, a sample with composition of x=0.4 is expected for heating by external field. Temperature increase depending on the magnetic field strength and frequency supported that samples with composition of x=0.2, 0.4 were appropriate for use as an agent in hyperthermia treatment.
机译:通过我们的新型湿化学方法制备了平均直径为12 nm的Fe3-xZnxO4(x = 0.2、0.4、0.6、0.8、1)纳米颗粒。用X射线衍射和超导量子干涉仪(SQUID)磁力计研究了所得颗粒的晶体结构和磁性。直流(DC)磁化强度测量结果表明,随着复合参数x的增加,矫顽力Hc和饱和磁化强度Ms减小。这种现象表明位于四面体A位点的Zn2 +离子会削弱四面体A位和八面体B位之间的超交换相互作用。从交流电的磁化率来看,预计x = 0.4的样品将通过外部磁场加热。温度升高取决于所支持的磁场强度和频率,以使x = 0.2、0.4的样品适合用作高温治疗剂。

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