A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors

Alcindo A. Dos Santos; Alfredo R. M. De Oliveira; Fabio Simonelli; Francisco De A. Marques; Giuliano C. Clososki; Paulo H. G. Zarbin

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A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors

机译：通过共轭加成氰尿酸恶唑啉到迈克尔受体上合成（±）-茉莉酸甲酯和（±）-baclofen的新方法

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摘要

A introdu??o de um grupamento equivalente ao anion carboximetil a enonas e nitroalquenos através da rea??o de adi??o 1,4 do cianocuprato da 2,4,4-trimetil-2-oxazolina 3, resulta numa metodologia interessante para a síntese de produtos naturais como (±)-metil jasmonato (1) e (±)-baclofen (2).

机译：通过2,4,4-三甲基-2-恶唑啉3氰基戊酸酯的1,4加成反应将相当于羧甲基阴离子的基团引入烯酮和硝基烯烃，产生了一种有趣的方法用于合成天然产物，例如（±）茉莉酸甲酯（1）和（±）-baclofen（2）。

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《Journal of the Brazilian Chemical Society》 |2001年第5期|共7页
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Alcindo A. Dos Santos; Alfredo R. M. De Oliveira; Fabio Simonelli; Francisco De A. Marques; Giuliano C. Clososki; Paulo H. G. Zarbin;
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中图分类生物物理学;
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1. A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors [J] . Clososki Giuliano C., Marques Francisco de A., Oliveira Alfredo R. M. de, Journal of the Brazilian Chemical Society . 2001,第5期

机译：通过共轭加成氰尿酸恶唑啉到迈克尔受体上合成（±）-茉莉酸甲酯和（±）-baclofen的新方法
2. EXPEDIENT SYNTHESIS OF 3,4-DIHYDROQUINAZOLINES VIA TANDEM ADDITION-CONJUGATE ADDITION CYCLIZATION OF CARBODIIMIDES BEARING A MICHAEL ACCEPTOR [J] . Takao Salto, Hayato Nakano, Hidenori Terada Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2012,第2期

机译：通过带有迈克尔受体的碳二亚胺的串联加成-共轭加成循环合成3,4-二氢喹啉类化合物
3. Copper-Catalyzed Asymmetric Conjugate Additions of Bis(pinacolato)diboron and Dimethylzinc to Acyl-N-methylimidazole Michael Acceptors: A Highly Stereoselective Unified Strategy for 1,3,5,...n (OH, Me) Motif Synthesis [J] . Lauberteaux Jimmy, Crevisy Christophe, Basle Olivier, Organic letters . 2019,第6期

机译：铜催化的不对称缀合物的双（Pinacolato）二硼和二甲基锌加入酰基-N-甲基咪唑迈克尔受体：1,3,5的高度立体化统一策略，...... N（哦，ME）基序合成
4. Michael Addition Reactions between Nucleophilic GlycineEquivalents and Acrylic Acid Derivatives as a Practicaland Generalized Approach to the Asymmetric Synthesisof II-Substituted-a-Amino Acids [C] . Vadim A. Soloshonok, Hisanori Ueki, Trevor K. Ellis ACS symposium asymmetric synthesis and application of α-amino acids . 2009

机译：亲核糖糖糖尿剂与丙烯酸衍生物之间的迈克尔添加反应作为不对称合成的不对称 - A-氨基酸的不对称方法的普遍化方法
5. Enantioselective conjugate additions to Meldrum's acid acceptors for the synthesis of quaternary centres and studies on persistent intramolecular carbon-hydrogen-X (X = oxygen, sulfur, bromium, chlorine, and fluorine) hydrogen bonds involving benzyl Meldrum's acids [D] . Wilsily, Ashraf 2009

机译：向Meldrum的酸受体进行对映选择性共轭加成，以合成季中心，并研究涉及苄基Meldrum酸的持久性分子内碳氢X（X =氧，硫，溴，氯和氟）氢键
6. Copper-catalyzed enantioselective conjugate addition of organometallic reagents to challenging Michael acceptors [O] . Delphine Pichon, Jennifer Morvan, Christophe Crévisy, 2020

机译：铜催化的对映选择性缀合物加入有机金属试剂以攻击迈克尔受体
7. A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors [O] . Alcindo A. dos Santos, Giuliano C. Clososki, Fabio Simonelli, 2001

机译：通过共轭加入的恶唑啉氰基丙酸盐与迈克尔受体的共轭加入（±） - 茉莉甲基己酸酯和（±） - （±）的新方法

A new approach to the synthesis of (±)-methyl jasmonate and (±)-baclofen via conjugated addition of oxazoline cyanocuprate to Michael acceptors

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