Crystal structure of the tetra-hydro-furan disolvate of a 94:6 solid solution of [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II) and its monophosphine oxide analogue

Rotter M.; Mastalir M.; Glatz M.; St?ger B.; Kirchner K.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of the tetra-hydro-furan disolvate of a 94:6 solid solution of [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II) and its monophosphine oxide analogue

【24h】

Crystal structure of the tetra-hydro-furan disolvate of a 94:6 solid solution of [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II) and its monophosphine oxide analogue

机译：[N2，N6-双-（二叔丁基-膦基-吡啶基）吡啶-2,6-二胺]-二溴锰的94：6固溶体的四氢呋喃二溶剂化物的晶体结构（II）及其一氧化膦类似物

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The MnBr2 complex of N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine (1·MnBr2) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O·MnBr2) and two tetra-hydro-furan (THF) mol-ecules, namely [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II)–[bis-(di-tert-butyl-phosphan-yl)({6-[(di-tert-butyl-phosphan-yl)amino]-pyridin-2-yl}amino)-phosphine oxide]di-bromido-manganese(II)–tetra-hydro-furan (0.94/0.06/2), [MnBr2(C21H41N3P2)]0.94[MnBr2(C21H41N3OP2)]0.06·2C4H8O. The 1·MnBr2 and 1O·MnBr2 complexes are occupationally disordered about general positions. Both complexes feature square-pyramidal coordination of the MnII atoms. They are connected by weak N—H?Br hydrogen bonding into chains extending along [001]. The THF mol-ecules are located between the layers formed by these chains. One THF mol-ecule is involved in hydrogen bonding to an amine H atom.

机译：N2，N6-双-（二叔丁基-膦基-基）吡啶-2,6-二胺（1·MnBr2）的MnBr2配合物与5.69％的单膦氧化物类似物（1O·MnBr2）共结晶）和两个四氢呋喃（THF）mol-ecule，即[N2，N6-双-（二叔丁基-膦基-吡啶基）吡啶-2,6-二胺]-二溴锰（II ）-[双-（二叔丁基-膦基-基）（{6-[（二叔丁基-膦基-基）氨基]-吡啶-2-基}氨基）-氧化膦]二溴代-锰（II）-四氢呋喃（0.94 / 0.06 / 2），[MnBr2（C21H41N3P2）] 0.94 [MnBr2（C21H41N3OP2）] 0.06·2C4H8O。 1·MnBr2和1O·MnBr2络合物在一般位置上在职业上无序。两种络合物均具有MnII原子的方金字塔形配位。它们通过弱的NHBr氢键连接成沿着[001]延伸的链。 THF分子位于这些链形成的层之间。一种THF分子与氢键合到胺H原子上。

著录项

来源
《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第9期|共4页
作者
Rotter M.; Mastalir M.; Glatz M.; St?ger B.; Kirchner K.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. Crystal structure of the tetra-hydro-furan disolvate of a 94:6 solid solution of [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II) and its monophosphine oxide analogue [J] . Rotter M., Mastalir M., Glatz M., Acta Crystallographica Section E: Crystallographic Communications . 2017,第9期

机译：[N2，N6-双-（二叔丁基-膦基-吡啶基）吡啶-2,6-二胺]-二溴锰的94：6固溶体的四氢呋喃二溶剂化物的晶体结构（II）及其一氧化膦类似物
2. Effects of #beta#-cyclodextrin inclusion on the kinetics of the oxidation of bisferrocenyl cations by bis(pyridine-2,6-dicarboxylato)-cobaltate(III) in aqueous solution: crystal structure of dimethyldi-(1-methylferrocene)ammonium bromide [J] . Donal H. Macartney, Aleksander W. Roszak, K. Christopher Smith Inorganica Chimica Acta . 1999,第1a2期

机译：＃β＃-环糊精包合物对水溶液中双（吡啶-2,6-二羧基）-钴（III）氧化双二茂铁基阳离子动力学的影响：二甲基二-（1-甲基二茂铁）溴化铵的晶体结构
3. Syntheses, crystal, and molecular structures of Mn(II), Zn(II), and Ce(III) compounds and solution studies of Mn(II), Ni(II), Cu(II), Zn(II), Cd(II), and Ce(III) compounds obtained from a suitable proton transfer compound containing bda and pydcH_2 (bda = butane-1,4-diamine; pydcH_2 = pyridine-2,6-dicarboxylic acid) [J] . Aghabozorg H., Roshan L., Firoozi N., Structural Chemistry . 2010,第4期

机译：Mn（II），Zn（II）和Ce（III）化合物的合成，晶体和分子结构以及Mn（II），Ni（II），Cu（II），Zn（II），Cd（ II），以及从含有bda和pydcH_2（bda =丁烷-1,4-二胺; pydcH_2 =吡啶-2,6-二羧酸）的合适质子转移化合物获得的Ce（III）化合物
4. SYNTHESIS AND CRYSTAL STRUCTURE OF NOVEL NONSTOICHIOMETRIC SUBOXIDE SOLID SOLUTIONS, Ti_(12-δ)Ga_xBi_(3-x)O_(10) [C] . Hisanori Yamane, Shinsaku Amano Conference on nonstoichiometric compounds . 2019

机译：新型非化学计量的硫化物Ti_（12-δ）Ga_xBi_（3-x）O_（10）的合成及晶体结构
5. Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of N2N6-bis(di-tert-butylphosphanyl)pyridine-26-diaminedibromidomanganese(II) and its monophosphine oxide analogue [O] . Markus Rotter, Matthias Mastalir, Mathias Glatz, 2017

机译：94：6 N固溶体的四氢呋喃二溶剂化物的晶体结构2N6-双（二叔丁基膦烷基）吡啶-26-二胺 br二溴锰（II）及其一氧化膦类似物
6. Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N2,N6-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue [O] . Markus Rotter, Matthias Mastalir, Mathias Glatz, 2017

机译：[N2，N6-双（二叔丁基磷烷基）吡啶-2,6-二胺]二溴二胺（Ⅱ）及其单膦氧化物类似物的94：6固溶体的四氢呋喃溶剂化物的晶体结构

Crystal structure of the tetra-hydro-furan disolvate of a 94:6 solid solution of [N2,N6-bis-(di-tert-butyl-phosphan-yl)pyridine-2,6-di-amine]-dibromido-manganese(II) and its monophosphine oxide analogue

摘要

著录项

相似文献

相关主题

期刊订阅