[N′-(4-Dec-yloxy-2-oxido-benzyl-idene)-3-hy-droxy-2-naphtho-hydrazidato-κ3N,O,O′]di-methyl-tin(IV): crystal structure and Hirshfeld surface analysis

Rosely S.N.B.M.; Hussen R.S.D.; Lee S.M.; Halcovitch N.R.; Jotani M.M.; Tiekink E.R.T.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >[N′-(4-Dec-yloxy-2-oxido-benzyl-idene)-3-hy-droxy-2-naphtho-hydrazidato-κ3N,O,O′]di-methyl-tin(IV): crystal structure and Hirshfeld surface analysis

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[N′-(4-Dec-yloxy-2-oxido-benzyl-idene)-3-hy-droxy-2-naphtho-hydrazidato-κ3N,O,O′]di-methyl-tin(IV): crystal structure and Hirshfeld surface analysis

机译：[N'-（4-癸氧基-2-氧化苄基亚乙基）-3-羟基-2-萘肼基-κ3N，O，O']二甲基-锡（IV）：晶体结构和Hirshfeld表面分析

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The title diorganotin compound, [Sn(CH3)2(C28H32N2O4)], features a distorted SnC2NO2 coordination geometry almost inter-mediate between ideal trigonal–bipyramidal and square-pyramidal. The dianionic Schiff base ligand coordinates in a tridentate fashion via two alkoxide O and hydrazinyl N atoms; an intra-molecular hy-droxy-O—H?N(hydrazin-yl) hydrogen bond is noted. The alk-oxy chain has an all-trans conformation, and to the first approximation, the mol-ecule has local mirror symmetry relating the two Sn-bound methyl groups. Supra-molecular layers sustained by imine-C—H?O(hy-droxy), π–π [between dec-yloxy-substituted benzene rings with an inter-centroid separation of 3.7724?(13)??], C—H?π(arene) and C—H?π(chelate ring) inter-actions are formed in the crystal; layers stack along the c axis with no directional inter-actions between them. The presence of C—H?π(chelate ring) inter-actions in the crystal is clearly evident from an analysis of the calculated Hirshfeld surface.

机译：标题二有机锡化合物[Sn（CH3）2（C28H32N2O4）]具有扭曲的SnC2NO2配位几何结构，几乎介于理想的三角-双锥体和正方形-锥体之间。二价阴离子席夫碱配体通过两个醇盐O和肼基N原子以三齿形式配位。注意到分子内的羟基-OH-N（肼基）氢键。烷氧基链具有全反式构象，并且对于第一近似，该分子具有与两个Sn结合的甲基相关的局部镜像对称性。由亚胺-CH 2 O（羟基），π-π（在癸氧基取代的苯环之间，质心间间距为3.7724？（13）??）维持的超分子层，CH晶体中形成ππ（芳烃）与CHππ（螯合物环）的相互作用。层沿c轴堆叠，它们之间没有方向性的相互作用。通过对计算的Hirshfeld表面的分析，可以清楚地看出晶体中存在CH-π（螯合环）相互作用。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第3期|共7页
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Rosely S.N.B.M.; Hussen R.S.D.; Lee S.M.; Halcovitch N.R.; Jotani M.M.; Tiekink E.R.T.;
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[N′-(4-Dec-yloxy-2-oxido-benzyl-idene)-3-hy-droxy-2-naphtho-hydrazidato-κ3N,O,O′]di-methyl-tin(IV): crystal structure and Hirshfeld surface analysis

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