Crystal structures of two alkaline earth (M = Ba and Sr) dimanganese(II) iron(III) tris-(orthophosphates)

Alhakmi G.; Assani A.; Saadi M.; El Ammari L.

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Crystal structures of two alkaline earth (M = Ba and Sr) dimanganese(II) iron(III) tris-(orthophosphates)

机译：两种碱土金属（M = Ba和Sr）二锰（II）铁（III）三（正磷酸盐）的晶体结构

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Two new orthophosphates, BaMn2Fe(PO4)3 [barium dimanganese(II) iron(III) tris-(orthophosphate)] and SrMn2Fe(PO4)3 [strontium dimanganese(II) iron(III) tris-(orthophosphate)], were synthesized by solid-state reactions. They are isotypic and crystallize in the ortho-rhom-bic system with space group type Pbcn. Their crystal structures comprise infinite zigzag chains of edge-sharing FeO6 octa-hedra (point group symmetry .2.) and Mn2O10 double octa-hedra running parallel to [001], linked by two types of PO4 tetra-hedra. The so-formed three-dimensional framework delineates channels running along [001], in which the alkaline earth cations (site symmetry .2.) are located within a neighbourhood of eight O atoms.

机译：合成了两种新的正磷酸盐BaMn2Fe（PO4）3 [三锰正磷酸钡（II）和SrMn2Fe（PO4）3 [正磷酸三锰锶（II）锶]。通过固态反应。它们是同型的，并且在空间群类型为Pbcn的正交斜方晶系中结晶。它们的晶体结构包括边缘共享的FeO6八面体（点组对称性.2。）和Mn2O10双八面体平行于[001]的无限之字形链，由两种类型的PO4四面体连接。如此形成的三维框架描述了沿[001]延伸的通道，其中碱土金属阳离子（位点对称性2.）位于8个O原子附近。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2017年第5期|共4页
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Alhakmi G.; Assani A.; Saadi M.; El Ammari L.;
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1. Crystal structure of strontium dicobalt iron(III) tris-(orthophosphate): SrCo2Fe(PO4)3 [J] . Bouraima A., Makani T., Assani A., Acta Crystallographica Section E: Crystallographic Communications . 2016,第8期

机译：三（正磷酸盐）锶二钴铁的晶体结构：SrCo2Fe（PO4）3
2. Crystal structure of calcium dinickel(II) iron(III) tris-(orthophosphate): CaNi2Fe(PO4)3 [J] . Ouaatta S., Assani A., Saadi M., Acta Crystallographica Section E: Crystallographic Communications . 2017,第6期

机译：三（正磷酸）钙二镍（II）铁（III）的晶体结构：CaNi2Fe（PO4）3
3. Crystal structure of calcium dinickel(II) iron(III) tris-(orthophosphate): CaNi2Fe(PO4)3 [J] . Ouaatta S., Assani A., Saadi M., Acta Crystallographica Section E: Crystallographic Communications . 2017,第6期

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4. Transformation of Iron(VI) into Iron(III) in the Presence of Chelating Agents: A Frozen Solution Moessbauer Study: Moessbauer Investigation of the Reaction between Iron(VI) and Chelating Agents in Alkaline Medium [C] . Symposium on ferrates : Synthesis, properties, and applications in water and wastewater treatment . 2008

机译：在螯合剂存在下铁（vi）在螯合剂的情况下转化为铁（III）：冷冻溶液Moessbauer研究：Moessbauer对碱性介质中的铁（VI）和螯合剂之间的反应研究
5. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

机译：Ru和Mn的一系列高价羰基配合物的结构和反应性：Ru（III）介导的三苯膦催化氧化，双核Mn（III，III）和Mn（III，IV）二聚体的表征以及单核铁（III）和铁（IV）。
6. Crystal structures of two alkaline earth (M = Ba and Sr) dimanganese(II) iron(III) tris(orthophosphates) [O] . Ghaleb Alhakmi, Abderrazzak Assani, Mohamed Saadi, 2017

机译：两种碱土金属（M = Ba和Sr）二锰（II）铁（III）三（正磷酸盐）的晶体结构
7. Crystal structures of two alkaline earth (M = Ba and Sr) dimanganese(II) iron(III) tris(orthophosphates) [O] . Ghaleb Alhakmi, Abderrazzak Assani, Mohamed Saadi, 2017

机译：两种碱土（m = Ba和sr）二锰（II）铁（III）三（正磷酸盐）的晶体结构

Crystal structures of two alkaline earth (M = Ba and Sr) dimanganese(II) iron(III) tris-(orthophosphates)

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