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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >A non-solvated form of [(Z)-O-methyl-N-(2-methyl-phen-yl)-thio-carbamato-κS](tri-phenyl-phosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis
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A non-solvated form of [(Z)-O-methyl-N-(2-methyl-phen-yl)-thio-carbamato-κS](tri-phenyl-phosphane-κP)gold(I): crystal structure and Hirshfeld surface analysis

机译：[（Z）-O-甲基-N-（2-甲基-苯基）-硫代氨基甲酸酯-κS]（三苯基膦-κP）金的非溶剂化物形式（金）：晶体结构和Hirshfeld表面分析

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摘要

The title compound, [Au(C9H10NOS)(C18H15P)], features a near linear P—Au—S arrangement defined by phosphane P and thiol-ate S atoms with the minor distortion from the ideal [P—Au—S is 177.61?(2)°] being traced in part to the close intra-molecular approach of an O atom [Au?O = 3.040?(2)??]. The packing features supra-molecular layers lying parallel to (011) sustained by a combination of C—H?π and π–π [inter-centroid distance = 3.8033?(17)??] inter-actions. The mol-ecular structure and packing are compared with those determined for a previously reported hemi-methanol solvate [Kuan et al. (2008). CrystEngComm, 10, 548–564]. Relatively minor differences are noted in the conformations of the rings in the Au-containing mol-ecules. A Hirshfeld surface analysis confirms the similarity in the packing with the most notable differences relating to the formation of C—H?S contacts between the constituents of the solvate.
机译：标题化合物[Au（C9H10NOS）（C18H15P）]具有由膦P和硫醇酸酯S原子定义的近似线性的P-Au-S排列，与理想的[P-Au-S相比，畸变较小，为177.61？ （2）°]部分归因于O原子的接近分子内接近[Au 2 O ＝3.040π（2）-3]。堆积具有与（011）平行的超分子层，由CH-π和π-π[质心间距离= 3.8033？（17）??]相互作用共同维持。将分子结构和堆积与先前报道的半甲醇溶剂化物[Kuan et al。 （2008）。 CrystEngComm，10，548–564]。在含Au的分子中环的构型中观察到相对较小的差异。 Hirshfeld表面分析证实了填料的相似性，其中最明显的不同之处在于溶剂化物各组分之间的CHS接触的形成。

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