...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >μ3-Chlorido-μ2-chlorido-(μ3-pyrrolidine-1-carbo-dithio-ato-κ4S:S,S′:S′)tris-[(tri-ethyl-phosphane-κP)copper(I)]: crystal structure and Hirshfeld surface analysis
【24h】

μ3-Chlorido-μ2-chlorido-(μ3-pyrrolidine-1-carbo-dithio-ato-κ4S:S,S′:S′)tris-[(tri-ethyl-phosphane-κP)copper(I)]: crystal structure and Hirshfeld surface analysis

机译：μ3-氯-μ2-氯-（μ3-吡咯烷-1-羰基-二硫代-κ4S：S，S'：S'）tris-[（（三乙基膦-κP）铜（I）]]：晶体结构和Hirshfeld表面分析

获取原文
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

The title trinuclear compound, [Cu3(C5H8NS2)Cl2(C6H15P)3], has the di-thio-carbamate ligand symmetrically chelating one CuI atom and each of the S atoms bridging to another CuI atom. Both chloride ligands are bridging, one being μ3- and the other μ2-bridging. Each Et3P ligand occupies a terminal position. Two of the CuI atoms exist within Cl2PS donor sets and the third is based on a ClPS2 donor set, with each coordination geometry based on a distorted tetra-hedron. The constituents defining the core of the mol-ecule, i.e. Cu3Cl2S2, occupy seven corners of a distorted cube. In the crystal, linear supra-molecular chains along the c axis are formed via phosphane–methyl-ene-C—H?Cl and pyrrolidine–methyl-ene-C—H?π(chelate) inter-actions, and these chains pack without directional inter-actions between them. An analysis of the Hirshfeld surface points to the predominance of H atoms at the surface, i.e. contributing 86.6% to the surface, and also highlights the presence of C—H?π(chelate) inter-actions.
机译：标题三核化合物[Cu3（C5H8NS2）Cl2（C6H15P）3]具有二硫代氨基甲酸酯配体，其对称地螯合一个CuI原子，每个S原子桥接至另一个CuI原子。两个氯化物配体都桥接，一个是μ3-桥接，另一个是μ2-桥接。每个Et3P配体占据一个末端位置。 Cu2原子供体集中存在两个CuI原子，第三个原子基于ClPS2供体集中，每个配位几何均基于扭曲的四面体。定义分子核心的成分，即Cu3Cl2S2，占据了扭曲立方体的七个角。在晶体中，通过膦-甲基-C-H 2 Cl与吡咯烷-甲基-C-H 2π（螯合物）相互作用形成沿c轴的线性超分子链，这些链堆积它们之间没有方向性的交互作用。对Hirshfeld表面的分析指出了表面H原子的占主导地位，即对表面贡献了86.6％，并且还强调了C-H？π（螯合物）相互作用的存在。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号