Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ2O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate

Sudheer R.; Sithambaresan M.; Sajitha N.R.; Manoj E.; Kurup M.R.P.

首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of aqua[(E)-N′-(5-bromo-2-oxidobenzylidene-κO)benzohydrazidato-κ2O,N′]dioxidomolybdenum(VI) dimethylformamide monosolvate

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Crystal structure of aqua[(E)-N′-(5-bromo-2-oxidobenzylidene-κO)benzohydrazidato-κ2O,N′]dioxidomolybdenum(VI) dimethylformamide monosolvate

机译：水（（E）-N'-（5-溴-2-氧化苄叉基-κO）苯并肼基-κ2O，N']二氧化钼（VI）二甲基甲酰胺单溶剂化物的晶体结构

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The title compound, [Mo(C14H9BrN2O2)O2(H2O)]·C3H7NO, has a distorted octahedral geometry around the Mo atom, with the two terminal oxide groups lying cis to each other. The two aromatic rings present in the molecule are almost coplanar, forming a dihedral angle of 1.4 (2)°. The five-membered ring involving the metal atom is puckered, with an amplitude Q = 0.358 (2) Å and φ = 204.1 (6)°. In the crystal, pairs of inversion-related molecules are linked by O—H⋯N hydrogen bonds. An O—H⋯O hydrogen bond connects the water ligand to the dimethylformamide solvent molecule. The crystal packing also features π–π [centroid–centroid distance of 3.688 (2) Å] and C—H⋯O interactions.

机译：标题化合物[Mo（C14H9BrN2O2）O2（H2O）]·C3H7NO在Mo原子周围具有扭曲的八面体几何形状，两个末端氧化物基团彼此顺式排列。分子中存在的两个芳环几乎共面，形成1.4（2）°的二面角。褶皱涉及金属原子的五元环，其振幅Q = 0.358（2）Å，φ= 204.1（6）°。在晶体中，成对的反转相关分子通过O-H⋯N氢键连接。一个OH = O的氢键将水配体连接到二甲基甲酰胺溶剂分子上。晶体堆积物还具有π–π [质心-质心距离为3.688（2）Å]和C-H⋯O相互作用。

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《Acta Crystallographica Section E: Crystallographic Communications》 |2015年第6期|共4页
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Sudheer R.; Sithambaresan M.; Sajitha N.R.; Manoj E.; Kurup M.R.P.;
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1. Crystal structure of aqua[(E)-N′-(5-bromo-2-oxidobenzylidene-κO)benzohydrazidato-κ2O,N′]dioxidomolybdenum(VI) dimethylformamide monosolvate [J] . Sudheer R., Sithambaresan M., Sajitha N.R., Acta Crystallographica Section E: Crystallographic Communications . 2015,第6期

机译：水（（E）-N'-（5-溴-2-氧化苄叉基-κO）苯并肼基-κ2O，N']二氧化钼（VI）二甲基甲酰胺单溶剂化物的晶体结构
2. Crystal structure of catena-poly[[[aquabis(dimethylformamide-κO)magnesium(II)]-μ3-(2,2′-bipyridine-5,5′-dicarboxylato-κ5O2:O2′:N,N′:O5)-[dichloridoplatinum(II)]] dimethylformamide monosolvate] [J] . Lundvall F., Tilset M. Acta Crystallographica Section E: Crystallographic Communications . 2017,第7期

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3. Crystal structure of N′-[(E)-3,5-dichloro-2-hydroxybenzylidene]-4-nitrobenzohydrazide dimethylformamide monosolvate [J] . Joseph B., Sajitha N.R., Sithambaresan M., Acta Crystallographica Section E: Crystallographic Communications . 2015,第11期

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5. Crystal structure of aqua(E)-N′-(5-bromo-2-oxidobenzylidene-κO)benzohydrazidato-κ2ON′dioxidomolybdenum(VI) dimethylformamide monosolvate [O] . Radhika Sudheer, M. Sithambaresan, N. R. Sajitha, 2015

机译：水基（E）-N-（5-溴-2-氧化苄基亚叉基-κO）苯并肼基-κ2的晶体结构ON二氧化钼（VI）二甲基甲酰胺单溶剂化物
6. Crystal structure of aqua[(E)-N′-(5-bromo-2-oxidobenzylidene-κO)benzohydrazidato-κ2O,N′]dioxidomolybdenum(VI) dimethylformamide monosolvate [O] . Radhika Sudheer, M. Sithambaresan, N. R. Sajitha, 2015

机译：aqua [（E）-N' - （5-溴-2-氧亚苄基-κO）苯并肼基-κ2O，N']二氧代钼（VI）二甲基甲酰胺单溶剂化物的晶体结构

Crystal structure of aqua­[(E)-N′-(5-bromo-2-oxido­benzyl­idene-κO)benzohydrazidato-κ2O,N′]dioxidomolybdenum(VI) di­methyl­formamide monosolvate

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Crystal structure of aqua[(E)-N′-(5-bromo-2-oxidobenzylidene-κO)benzohydrazidato-κ2O,N′]dioxidomolybdenum(VI) dimethylformamide monosolvate