TEMPO-catalyzed oxidative homocoupling route to 3,2′-biindolin-2-ones <em>via</em> an indolin-3-one intermediate

Bo Yin; Panpan Huang; Yingbing Lu; Liangxian Liu

首页> 外文期刊>RSC Advances >TEMPO-catalyzed oxidative homocoupling route to 3,2′-biindolin-2-ones via an indolin-3-one intermediate

【24h】

TEMPO-catalyzed oxidative homocoupling route to 3,2′-biindolin-2-ones via an indolin-3-one intermediate

机译：TEMPO催化吲哚-3-酮中间体氧化制取3,2′-联吲哚-2-酮的信号

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A combinative C2-selective arylation, and C3-selective carbonylation of free indole derivatives, by means of TEMPO catalysis and a silver oxidant under non-directing group conditions, was successful demonstrated. This new methodology is both atom and step efficient and is applicable to a broad scope of substrates, allowing the synthesis of a range of synthetically valuable 3,2′-biindolin-2-ones in moderate to excellent yields.

机译：在非定向基团条件下，通过TEMPO催化和银氧化剂，成功地证明了游离吲哚衍生物的C2选择性芳基化和C3选择性羰基化。这种新方法既原子又有效，并且适用于多种底物，从而可以中等至极高的产率合成一系列具有合成价值的3,2'-联吲哚-2-酮。

著录项

来源
《RSC Advances》 |2017年第2期|共5页
作者
Bo Yin; Panpan Huang; Yingbing Lu; Liangxian Liu;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Silver-catalyzed TEMPO oxidative homocoupling of indoles for the synthesis of 3,3 '-biindolin-2-ones [J] . Lin Feng, Chen Yu, Wang Baoshuang, RSC Advances . 2015,第46期

机译：银催化吲哚的TEMPO氧化均偶联反应合成3,3'-联吲哚-2-酮
2. A novel route to the 5,6-dihydro-4-h-thieno[3,2-b]pyrrol-5-one ring system involving an intermediate substituted-thiophene synthesis [J] . Hu SH, Huang YZ, Poss MA, Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2005,第4期

机译：涉及中间取代噻吩合成的5,6-二氢-4-h-噻吩并[3,2-b]吡咯-5-酮环系统的新途径
3. One new route to optimize the oxidation resistance of TiC/hastelloy (Ni-based alloy) composites applied for intermediate temperature solid oxide fuel cell interconnect by increasing graphite particle size [J] . Qi Qian, Liu Yan, Wang Lujie, Journal of power sources . 2017,第sepa15期

机译：一种通过增加石墨颗粒尺寸来优化用于中温固体氧化物燃料电池互连的TiC / Hastelloy（镍基合金）复合材料的抗氧化性的新途径
4. Nafion-metallic oxides membranes for intermediate temperature PEMFC [C] . L. Gonzalez-Rodriguez, J. Rodriguez, N. Rojas World Hydrogen Energy Conference . 2017

机译：Nafion-Metallic氧化物中间温度PEMFC的膜
5. Elucidating the mechanisms of copper-catalyzed aerobic transformations: From oxidative coupling of boronic acids and nucleophiles to copper/tempo-catalyzed alcohol oxidation. [D] . Ryland, Bradford L. 2013

机译：阐明铜催化的有氧转化的机理：从硼酸和亲核试剂的氧化偶联到铜/速度催化的醇氧化。
6. Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems [O] . Jessica M. Hoover, Bradford L. Ryland, Shannon S. Stahl -1

机译：铜/ TEMPO催化的好氧醇氧化：不同催化剂体系的机理评估
7. Carrier Pathway for Photoelectrochemical Water Oxidation with Intermediate State in ntype GaN Compared with Route of Anodic Corrosion [O] . -1

机译：与阳极腐蚀的途径相比，NTYPE GaN中中间状态的光电化学水氧化的载体路径

TEMPO-catalyzed oxidative homocoupling route to 3,2′-biindolin-2-ones via an indolin-3-one intermediate

摘要

著录项

相似文献

相关主题

期刊订阅