Silver-catalyzed TEMPO oxidative homocoupling of indoles for the synthesis of 3,3 '-biindolin-2-ones

Lin Feng; Chen Yu; Wang Baoshuang; Qin Wenbing; Liu Liangxian

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Silver-catalyzed TEMPO oxidative homocoupling of indoles for the synthesis of 3,3 '-biindolin-2-ones

机译：银催化吲哚的TEMPO氧化均偶联反应合成3,3'-联吲哚-2-酮

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An oxidative homo dimerization of free indole derivatives, bymeans of silver catalysis and TEMPO oxidant, was first successful demonstrated. This new methodology is both atom and step efficient and is applicable to a broad scope of substrates, allowing the synthesis of a range of synthetically valuable substituted C3-C3' bisindolin-2-ones in moderate to excellent yields.

机译：首次成功地证明了通过银催化和TEMPO氧化剂对游离吲哚衍生物的氧化均二聚。这种新的方法既原子又高效，并且适用于广泛的底物，从而可以中等至极好的收率合成一系列具有合成价值的取代的C3-C3'双吲哚-2-酮。

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《RSC Advances》 |2015年第46期|共5页
作者
Lin Feng; Chen Yu; Wang Baoshuang; Qin Wenbing; Liu Liangxian;
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1. Silver-catalyzed TEMPO oxidative homocoupling of indoles for the synthesis of 3,3 '-biindolin-2-ones [J] . Lin Feng, Chen Yu, Wang Baoshuang, RSC Advances . 2015,第46期

机译：银催化吲哚的TEMPO氧化均偶联反应合成3,3'-联吲哚-2-酮
2. Metal-free Catalyzed Oxidative Trimerization of Indoles by Using TEMPO in Air: An Entry into 3-(1H-indol-3-yl)-3,3'-biindolin-2-ones [J] . Wen-Bing Qin, Qiong Chang, Hai-Qinq Luo, Current Organic Synthesis . 2013,第3期

机译：空气中使用TEMPO的无金属催化的吲哚氧化三聚：进入3-（1H-吲哚-3-基）-3,3'-联吲哚-2-酮
3. TEMPO-catalyzed oxidative homocoupling route to 3,2′-biindolin-2-ones via an indolin-3-one intermediate [J] . Bo Yin, Panpan Huang, Yingbing Lu, RSC Advances . 2017,第2期

机译：TEMPO催化吲哚-3-酮中间体氧化制取3,2′-联吲哚-2-酮的信号
4. Synthesis of Novel Symmetrical Macrocycle via Oxidative Homocoupling of Bisalkyne [C] . Nurulain Kamalulazmy, Nurul Izzaty Hassan UKM FST Postgraduate Colloquium . 2014

机译：双烷基氧化同耦合新型对称宏细胞
5. Natural indoles, indole-3-carbinol and 3,3'-diindolylmethane, counteract the effects of staphylococcal enterotoxin B-induced inflammation through epigenetic regulation and modulation of microRNA. [D] . Busbee, Philip Brandon. 2014

机译：天然吲哚，吲哚-3-甲醇和3,3'-二吲哚甲烷可通过表观遗传调控microRNA对抗葡萄球菌肠毒素B诱导的炎症。
6. Copper-Catalyzed Synthesis of N-Aryl and N-Sulfonyl Indoles from 2-Vinylanilines with O2 as Terminal Oxidant and TEMPO as Co-Catalyst [O] . Timothy W. Liwosz, Sherry R. Chemler -1

机译：以O2为末端氧化剂TEMPO为助催化剂的2-乙烯基苯胺的铜催化合成N-芳基和N-磺酰基吲哚
7. Correction: Metal-free oxidative coupling of arylmethylamines with indoles: a simple, environmentally benign approach for the synthesis of 3,3′-bis(indolyl)methanes [O] . Vikas D. Kadu, Sankala Naga Chandrudu, Mahesh G. Hublikar, 2021

机译：校正：芳基甲基胺的无金属氧化偶联与吲哚：一种简单，环境良好的合成3,3'-BIS（吲哚基）甲烷的方法

Silver-catalyzed TEMPO oxidative homocoupling of indoles for the synthesis of 3,3 '-biindolin-2-ones

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