The superior desorption properties of MgCl2-added ammonia borane compared to MgF2-added systems—the unexpected role of MgCl2 interacting with [NH3] units

Xiaoli Ding; Jingjing Feng; Tianlai Xia; Xiaomin Yuan; Dongming Liu; Yongtao Li; Qingan Zhang

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The superior desorption properties of MgCl₂-added ammonia borane compared to MgF₂-added systems—the unexpected role of MgCl₂ interacting with [NH₃] units

机译：与添加MgF _{2 的系统相比，添加MgCl _{2 的氨硼烷具有优异的脱附性能-MgCl _{2 与[NH]相互作用的出乎意料的作用_{3 ]个单位}}}}

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An uncommon dehydrogenation mechanism for metal chloride-added ammonia borane (NH₃BH₃, AB) systems revealed that MgCl₂ interacts with the [NH₃] units in AB, analogous to the amine complex of Mg(NH₃)_xCl₂, thus not only resulting in a remarkable decrease in the hydrogen desorption temperature but also effectively suppressing undesirable volatile by-products, particularly ammonia gas.

机译：添加金属氯化物的氨硼烷（NH _{3 BH _{3 ）的不常见脱氢机理表明： MgCl _{2 与AB中的[NH _{3 ]单元相互作用，类似于Mg（NH _{3 ） _{x Cl _{2 ，因此不仅导致氢解吸温度显着降低，而且还有效抑制了不希望的挥发性副产物，特别是氨气。}}}}}}} 展开▼

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《RSC Advances》 |2017年第58期|共4页

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Xiaoli Ding; Jingjing Feng; Tianlai Xia; Xiaomin Yuan; Dongming Liu; Yongtao Li; Qingan Zhang;
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中图分类化学;

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The superior desorption properties of MgCl2-added ammonia borane compared to MgF2-added systems—the unexpected role of MgCl2 interacting with [NH3] units

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The superior desorption properties of MgCl₂-added ammonia borane compared to MgF₂-added systems—the unexpected role of MgCl₂ interacting with [NH₃] units