Imidazolium-based ionic liquid-catalyzed hydrosilylation of imines and reductive amination of aldehydes using hydrosilane as the reductant

Bin Li; Shilin Zhang; Weizhen Wu; Lecheng Liang; Shaohua Jiang; Lu Chen; Yibiao Li

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Imidazolium-based ionic liquid-catalyzed hydrosilylation of imines and reductive amination of aldehydes using hydrosilane as the reductant

机译：基于咪唑鎓的离子液体催化的亚胺的氢化硅烷化和使用氢化硅烷作为还原剂的醛的还原胺化

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The first imidazolium-based ionic liquid-catalyzed hydrosilylation of imine and reductive amination of aldehydes with primary amines using a catalytic amount of 1-butyl-3-methylimidazolium tetrachloride iron [BMIm][FeCl₄] and Ph₂SiH₂ as a reductant were performed under mild conditions. Good yields of secondary amines with high chemoselectivity and a tolerance for a wide range of functional groups were obtained.

机译：催化量的1-丁基-3-甲基咪唑四氯化铁[BMIm] [FeCl _{4 催化的第一咪唑基离子液体催化的亚胺亚胺的氢化硅烷化反应和醛与伯胺的还原胺化反应]和Ph _{2 SiH _{2 作为还原剂在温和条件下进行。获得了具有高化学选择性和对多种官能团的耐受性的仲胺，具有良好的收率。}}}

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《RSC Advances》 |2017年第51期|共5页
作者
Bin Li; Shilin Zhang; Weizhen Wu; Lecheng Liang; Shaohua Jiang; Lu Chen; Yibiao Li;
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中图分类化学;
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1. Efficient Ruthenium(II)-Catalyzed Direct Reductive Amination of Aldehydes under Mild Conditions Using Hydrosilane as the Reductant [J] . Li Bin, Zheng Jianxiong, Zeng Weifeng, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2017,第6期

机译：高效钌（II） - 使用氢硅烷作为还原剂的温和条件下的醛直接还原胺化
2. Bronsted acid ionic liquid-catalyzed reductive Friedel-Crafts alkylation of indoles and cyclic ketones without using an external reductant [J] . Taheri Amir, Lai Bingbing, Cheng Chenga, Green chemistry . 2015,第2期

机译：不使用外部还原剂的布朗斯台德酸离子液体催化的吲哚和环状酮的还原弗里德-克来福特烷基化
3. Dichlorobis(1,4-diazabicyclo[2.2.2]octane)(tetrahydroborato)zirconium(IV), [Zr(BH_4)_2Cl_2(dabco)_2](ZrBDC), as a new, stable, and versatile bench top reducing agent: reduction of imines and enamines, reductive amination of aldehydes and ketones and [J] . Habibi Firouzabadi, Nasser Iranpoor, Heshmatollah Alinezhad Bulletin of the Chemical Society of Japan . 2003,第1期

机译：二氯双（1,4-二氮杂双环[2.2.2]辛烷）（四氢硼氢化）锆（IV），[Zr（BH_4）_2Cl_2（dabco）_2]（ZrBDC），是一种新型，稳定且用途广泛的台式还原剂：减少亚胺和烯胺，醛和酮的还原胺化
4. Use of GaH2 as A Reductive Hydride Source for Reduction of Ketones,Aldehydes and Imines [C] . Akiko Tsuhako, Mariko Mihara, Toshio Aida Symposium on Organometallic Chemistry . 2007

机译：使用Gah2作为还原氢化物源，用于还原酮，醛和亚胺
5. Biocatalytic Imine Reduction and Reductive Amination [D] . France, Scott P. 2018

机译：生物催化亚胺还原和还原胺化
6. Characterization of imine reductases in reductive amination for the exploration of structure-activity relationships [O] . Sarah L. Montgomery, Ahir Pushpanath, Rachel S. Heath, 2020

机译：表征还原性胺化中亚胺还原酶以探索构效关系
7. One-Pot, Two-Step Reductive Amination of Boronate Ester Containing Aromatic Amines and Aldehydes Using B2pin2 as Reductant [O] . Xueying Liu, Zhenwei Liu, Yuanyuan Guo, 2019

机译：使用B2Pin2含有芳族胺和醛作为还原剂的单壶，两步还原胺化含有芳族胺和醛的硼酸酯

Imidazolium-based ionic liquid-catalyzed hydrosilylation of imines and reductive amination of aldehydes using hydrosilane as the reductant

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