Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines

Romain Membrat; Alexandre Vasseur; Delphine Moraleda; Sabine Michaud-Chevallier; Alexandre Martinez; Laurent Giordano; Didier Nuel

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Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines

机译：铂-（次膦酸-次膦酸）络合物作为双敏催化剂，用于哌啶子醇的氧化裂解：伯胺的进入

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Platinum–(phosphinito–phosphinous acid) complex catalyzes the oxidative fragmentation of hindered piperidinols according to a hydrogen transfer induced methodology. This catalyst acts successively as both a hydrogen carrier and soft Lewis acid in a one pot – two steps process. This method can be applied to the synthesis of a wide variety of primary amines in a pure form by a simple acid–base extraction without further purification.

机译：根据氢转移诱导方法，铂-（次膦酸-次膦酸）络合物催化受阻哌啶子醇的氧化裂解。这种催化剂在一锅两步过程中既充当氢载体又充当软路易斯酸。该方法可通过简单的酸碱萃取而无需进一步纯化即可用于纯净形式的多种伯胺的合成。

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《RSC Advances》 |2019年第65期|共5页
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Romain Membrat; Alexandre Vasseur; Delphine Moraleda; Sabine Michaud-Chevallier; Alexandre Martinez; Laurent Giordano; Didier Nuel;
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1. Platinum-(phosphinito-phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines [J] . RSC Advances . 2019,第65期

机译：铂 - （磷碱 - 磷酸酸）复合物作为双天赋的哌啶醇氧化片段化的催化剂：对伯胺的进入
2. Phosphinous Acid Platinum Complex as Robust Catalyst for Oxidation: Comparison with Palladium and Mechanistic Investigations [J] . Romain Membrat, Alexandre Vasseur, Alexandre Martinez, European journal of organic chemistry . 2018,第39期

机译：磷酸铂复合物作为氧化稳健催化剂：与钯和机械研究相比
3. Bis(allyl)-ruthenium(IV) complexes with phosphinous acid ligands as catalysts for nitrile hydration reactions [J] . Tomas-Mendivil Eder, Francos Javier, Gonzalez-Fernandez Rebeca, Dalton transactions: An international journal of inorganic chemistry . 2016,第34期

机译：次膦酸配体的双（烯丙基）-钌（IV）配合物作为腈水合反应的催化剂
4. Zeolite-confined Mn complexes of cyclic amines: New selective catalysts for hydrocarbon oxidation [C] . D. E. De Vos, J. Meinershagen, T. Bein International congress on catalysis;ICC . 1996

机译：沸石限制的环胺锰配合物：新型的烃氧化选择性催化剂
5. Reactivity studies of platinum(IV) hydroxide and methoxide complexes and the study of pincer palladium(II) complexes as potential catalysts for olefin epoxidation [D] . Smythe, Nicole 2004

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7. Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines [O] . Romain Membrat, Alexandre Vasseur, Delphine Moraleda, 2019

机译：铂 - （磷碱 - 磷酸酸）复合物作为双天赋的哌啶醇氧化片段化的催化剂：对伯胺的进入
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Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines

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