Construction of highly functionalized naphthalenes using an in situ ene–allene strategy

Dianpeng Chen; Gangdong Xing; Jinzhong Yao; Hongwei Zhou

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Construction of highly functionalized naphthalenes using an in situ ene–allene strategy

机译：使用原位烯丙基苯丙烯策略构建高官能化萘甲苯

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Construction of highly functionalized naphthalene derivatives remains a challenging task for organic chemists because of the effect of the substituent. In this paper, we have developed a sequence of propargyl-allenyl isomerization and electrocyclization for the synthesis of polyfunctionalized naphthalenes.

机译：由于取代基的影响，高官能化萘衍生物的构建仍然是有机化学家具有具有挑战性的任务。在本文中，我们开发了一系列丙氨酸丙基 - 甲基异构化和电循环的合成序列，用于合成多官能化萘甲苯。

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《RSC Advances》 |2016年第105期|共4页
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Dianpeng Chen; Gangdong Xing; Jinzhong Yao; Hongwei Zhou;
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1. Construction of highly functionalized naphthalenes using an in situ ene-allene strategy [J] . Chen Dianpeng, Xing Gangdong, Yao Jinzhong, RSC Advances . 2016,第105期

机译：使用原位烯丙基苯丙烯策略构建高官能化萘甲苯
2. A metalation strategy for the construction of functionalized naphthalenes:the first synthesis of guieranone A [J] . Malcolm W.B.McCulloch, Russell A.Barrow Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第44期

机译：构造官能化萘的一种金属化策略：Gueranone A的首次合成
3. A metalation strategy for the construction of functionalized naphthalenes:the first synthesis of guieranone A [J] . Malcolm W.B.McCulloch, Russell A.Barrow Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第44期

机译：构造官能化萘的一种金属化策略：Gueranone A的首次合成
4. Synthesis and Characterization of Novel Thiol-Ene Hydrolyzing Films Containing Ene-Functionalized Isocyanate [C] . Nicole M. Mackey, Bridget S. Confait, Steven Stevenson, American Chemical Society . 2010

机译：烯酮官能化异氰酸酯的新型硫醇 - 烯水解膜的合成与表征
5. I. Chromium(III)-catalyzed carbometalation of alkynes. II. Chromium(III)-catalyzed synthesis of allenes via a syn-carbometalation/syn-elimination sequence. III. Palladium(0)-catalyzed synthesis of ene-allenes via cross-coupling reactions with alkenyl trifluoroborates. [D] . Sommers, Erin McGeehan. 2006

机译：I.铬（III）催化炔烃的碳金属化。二。铬（III）通过顺碳共金属/顺消除序列催化的丙二烯合成。三，钯（0）通过烯基三氟硼酸酯的交叉偶联反应催化烯-烯的合成。
6. Highly Sensitive Detection of Naphthalene in Solvent Vapor Using a Functionalized PBG Refractive Index Sensor [O] . Maiko Girschikofsky, Manuel Rosenberger, Stefan Belle, 2012

机译：使用功能化PBG折射率传感器高灵敏地检测溶剂蒸气中的萘
7. In situ construction of Co/N/C-based heterojunction on biomass-derived hierarchical porous carbon with stable active sites using a Co-N protective strategy for high-efficiency ORR, OER and HER trifunctional electrocatalysts [O] . Xuehui Lv, Zuoxu Xiao, Haoyuan Wang, 2021

机译：原位构建基于基于CO / N / C的异质结合生物质衍生的层级碳，使用CO-N保护策略进行稳定的活性位点，用于高效ORR，OER和三官能电催化剂
8. New Strategy for the Construction of Carbocyclic Alkenyl Silanes: The Synthesis of 1,1,2,2-Tetramethyl-1,2-Disilacyclopent-3-ene [R] . Sita, L. R., Lyon, S. R. 1989

机译：构建碳环烯基硅烷的新策略：1,1,2,2-四甲基-1,2-二硅杂环戊-3-烯的合成

Construction of highly functionalized naphthalenes using an in situ ene–allene strategy

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