A highly efficient heterogeneous copper-catalyzed Chan–Lam coupling reaction of sulfonyl azides with arylboronic acids leading to N-arylsulfonamides

Chongren You; Fang Yao; Tao Yan; Mingzhong Cai

首页> 外文期刊>RSC Advances >A highly efficient heterogeneous copper-catalyzed Chan–Lam coupling reaction of sulfonyl azides with arylboronic acids leading to N-arylsulfonamides

【24h】

A highly efficient heterogeneous copper-catalyzed Chan–Lam coupling reaction of sulfonyl azides with arylboronic acids leading to N-arylsulfonamides

机译：磺酰叠氮化物与芳基硼酸的高效非均相铜催化的Chan-am偶联反应导致N-芳基磺胺酰胺

获取原文

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A heterogeneous Chan–Lam coupling reaction between sulfonyl azides and arylboronic acids was achieved in MeOH at room temperature in the presence of 10 mol% of an L -proline-functionalized MCM-41-immobilized copper( I ) complex [MCM-41– L -proline–CuCl] under air, yielding a variety of N -arylsulfonamides in excellent yields. The new heterogeneous copper complex can be prepared from commercially readily available and inexpensive reagents, and recovered by simple filtration of the reaction solution and recycled at least 8 times without any decreases in activity.

机译：在室温下在10mol％的L-脯氨酸官能化的MCM-41固定铜（I）复合物[MCM-41-L的情况下，在室温下在室温下在MeOH之间实现非均相Chan-am偶联反应[MCM-41-L. - 在空气下 - 培脯氨酸 - CuCl，得到各种N-rall磺酰胺，其优异的产率。新的异质铜配合物可以由商业上易于获得的和廉价的试剂制备，并通过简单过滤反应溶液回收，并再循环至少8倍，而不会在活性中降低。

著录项

来源
《RSC Advances》 |2016年第49期|共8页
作者
Chongren You; Fang Yao; Tao Yan; Mingzhong Cai;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. A highly efficient heterogeneous copper-catalyzed Chan-Lam coupling reaction of sulfonyl azides with arylboronic acids leading to N-arylsulfonamides [J] . You Chongren, Yao Fang, Yan Tao, RSC Advances . 2016,第49期

机译：磺酰叠氮化物与芳基硼酸的高效非均相铜催化的Chan-am偶联反应导致N-芳基磺胺酰胺
2. A highly efficient heterogeneous copper-catalyzed Chan-Lam coupling between thiols and arylboronic acids leading to diaryl sulfides under mild conditions [J] . Lin Yang, Cai Mingzhong, Fang Zhigiang, Tetrahedron . 2016,第23期

机译：硫醇与芳基硼酸之间的高效异质铜催化Chan-Lam偶联在温和条件下导致二芳基硫醚
3. Copper-Catalyzed Chan?Lam Coupling between Sulfonyl Azides and Boronic Acids at Room Temperature [J] . Soo-Yeon Moon, Jungsoo Nam, Kris Rathwell, Organic letters . 2014,第2期

机译：室温下铜催化的磺酰叠氮化物与硼酸间的Chan-am偶联
4. Polymer-Bound Perfluoroalkyl Sulfonic Acids and Their Ytterbium Salts:Highly Efficient Versatile Catalysts for Organic Reactions [C] . 7th International Symposium on Green Chemistry in China(7th ISGCC'2005) . 2005

机译：聚合物结合的全氟烷基磺酸及其Y盐：用于有机反应的高效通用催化剂
5. Copper-Catalyzed Enantioselective Aza-Friedel-Crafts Addition of Phenols to N-Sulfonyl Aldimines and Oxidative Coupling of Alkyltrifluoroborates with Alkenols, Alkenoic Acids, and Alkenylamides [D] . Shikora, Jonathan Max. 2019

机译：铜催化的映选择性AZA-Friedel-Crafts加入苯酚与N-磺酰基醛胺和用链烯醇，链烯酸和链烯基酰胺的烷基三氟硼酸盐的氧化偶联
6. Electron-Poor Fluoro-Containing Arylboronic Acids as Efficient Coupling Partners for Bis(15-cyclooctadiene)nickel(0)/Tricyclohexylphosphine-Catalyzed Cross-Coupling Reactions of Aryl Arenesulfonates [O] . Dr. Wen-Bo Chen, Dr. Chun-Hui Xing, Jie Dong, -1

机译：贫电子含氟的芳基硼酸作为双（15-环辛二烯）镍（0）/三环己基膦催化的芳基芳烃磺酸盐交叉偶联反应的高效偶联剂
7. Chan–Lam coupling reaction of sulfamoyl azides with arylboronic acids for synthesis of unsymmetrical N-arylsulfamides [O] . Suk-Young Won, Seo-Eun Kim, Yong-Ju Kwon, 2019

机译：氨基酰肼与芳基硼酸合成非对称N-芳基磺胺酰胺的Chan-LAN偶联反应

A highly efficient heterogeneous copper-catalyzed Chan–Lam coupling reaction of sulfonyl azides with arylboronic acids leading to N-arylsulfonamides

摘要

著录项

相似文献

相关主题

期刊订阅