H2 activation using the first 1?:?1?:?1 hetero-tri(aryl)borane

Robin J. Blagg; Gregory G. Wildgoose

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H2 activation using the first 1?:?1?:?1 hetero-tri(aryl)borane

机译：H2使用前1的激活？：α1？：1杂 - 三（芳基）硼烷

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The novel 1?:?1?:?1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H _(2) with three Lewis bases.

机译：新颖的1？：α1？：α：1杂硼（芳基）硼烷（五氟苯基）{3,5-双（三氟甲基）苯基}（五氯苯基）硼烷已被合成并在结构上表征。这已被显示为用三种Lewis碱的H _（2）的甲烷基酸性分解的Lewis酸性组分。

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《RSC Advances》 |2016年第48期|共7页
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Robin J. Blagg; Gregory G. Wildgoose;
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1. H-2 activation using the first 1: 1: 1 hetero-tri(aryl) borane [J] . Blagg Robin J., Wildgoose Gregory G. RSC Advances . 2016,第48期

机译：H-2使用前1：1：1杂硼（芳基）硼烷活化
2. Reduction of Nitroarenes into Aryl Amines and N -Aryl hydroxylamines via Activation of NaBH 4 and Ammonia-Borane Complexes by Ag/TiO 2 Catalyst [J] . Dimitrios Andreou, Domna Iordanidou, Ioannis Tamiolakis, Nanomaterials . 2016,第3期

机译：Ag / TiO 2催化剂活化NaBH 4和氨-硼烷配合物将硝基芳烃还原为芳胺和N-芳基羟胺
3. Unexpected electronic process of H2 activation by a new nickel borane complex: Comparison with the usual homolytic and heterolytic activations [J] . Zeng G., Sakaki S. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第6期

机译：新的硼烷镍络合物意外地激活H2的电子过程：与通常的均相和杂合活化比较
4. Ph3 P-Mediated Synthesis of Functionalized 3-(Aryl)-1-phenyl-lif-pyrazoles from 1-ChIoro(aryl)methylene-2-phenylhydrazines and Activated Acetylenes??? [C] . European Symposium on Organic Chemistry . 2009

机译：pH3介导的官能化3-（芳基）-1-苯基 - LiF-吡唑的合成1- Chioro（芳基）亚甲基 -2-苯基肼和活化乙炔（乙炔）--??
5. Silylene and germylene activation of alkane, ether and amine carbon-hydrogen bonds mediated by an aryl halide. Observation of an aryl halide kinetic isotope effect for the carbon-hydrogenactivation reaction. [D] . Walker, Randon H. 2009

机译：芳基卤化物介导的烷烃，醚和胺的碳氢键的亚甲硅烷基和亚二甲基苯活化。碳-氢活化反应的芳基卤化物动力学同位素效应的观察。
6. Reduction of Nitroarenes into Aryl Amines and N-Aryl hydroxylamines via Activation of NaBH4 and Ammonia-Borane Complexes by Ag/TiO2 Catalyst [O] . Dimitrios Andreou, Domna Iordanidou, Ioannis Tamiolakis, 2016

机译：Ag / TiO2催化剂活化NaBH4和氨-硼烷配合物将硝基芳烃还原为芳胺和N-芳基羟胺
7. H2 activation using the first 1:1:1 hetero-tri(aryl)borane [O] . Blagg, Robin J., Wildgoose, Gregory G. 2016

机译：使用第一个1：1：1杂三（芳基）硼烷进行H2活化
8. Synthesis and X-ray Crystal Structures of (Au(CH2)2PPh2)2(CF3)2, (Au(CH2)2PPh2)2(C6F5)2, and (PPN)(Au(C6F5)4): Two Dinuclear Gold (II) Ylide Complexes Containing Alkyl and Aryl Ligands and a Tetrakis(pentafluorophenyl)aurate(III) [R] . Murray, H. H., Fackler, J. P., Porter, L. C., 1987

机译：（au（CH2）2pph2）2（CF3）2，（au（CH2）2pph2）2（C6F5）2和（ppN）（au（C6F5）4）的合成和X射线晶体结构：两个双核金（ II）含有烷基和芳基配体的Ylide配合物和四（五氟苯基）丙酸酯（III）

H2 activation using the first 1?:?1?:?1 hetero-tri(aryl)borane

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