Ru coordinated with BINAP in knitting aryl network polymers for heterogeneous asymmetric hydrogenation of methyl acetoacetate

Tao Wang; Yuan Lyu; Xingkun Chen; Cunyao Li; Miao Jiang; Xiangen Song; Yunjie Ding

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Ru coordinated with BINAP in knitting aryl network polymers for heterogeneous asymmetric hydrogenation of methyl acetoacetate

机译：Ru配位用Binap进行编织芳基网络聚合物，用于乙酰乙酸甲酯的非均相不对称氢化

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A facile method for the preparation of heterogeneous asymmetric hydrogenation catalysts was presented. BINAP was knitted with aryl compounds using formaldehyde dimethyl acetal (FDA) as a cross-linker by Friedel–Crafts reaction without any pre-modification. The prepared catalysts showed different catalytic activities, and excellent recyclablilty results could be achieved in asymmetric hydrogenation.

机译：提出了一种用于制备非均相不对称氢化催化剂的容易方法。使用甲醛二甲基缩醛（FDA）用芳基化合物编织Binap作为通过Friedel-Crafts反应的交联剂，而无需任何预修饰。制备的催化剂显示出不同的催化活性，并且可以在不对称的氢化中实现优异的循环结果。

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《RSC Advances》 |2016年第34期|共4页
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Tao Wang; Yuan Lyu; Xingkun Chen; Cunyao Li; Miao Jiang; Xiangen Song; Yunjie Ding;
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1. Ru coordinated with BINAP in knitting aryl network polymers for heterogeneous asymmetric hydrogenation of methyl acetoacetate [J] . Wang Tao, Lyu Yuan, Chen Xingkun, RSC Advances . 2016,第34期

机译：Ru配位用Binap进行编织芳基网络聚合物，用于乙酰乙酸甲酯的非均相不对称氢化
2. Synthesis and studies of 6,6 '-BINAP derivatives for the heterogeneous asymmetric hydrogenation of methyl acetoacetate [J] . Saluzzo C., Lamouille T., Le Guyader F., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2002,第11期

机译：乙酰乙酸甲酯非均相不对称氢化反应的6,6'-BINAP衍生物的合成与研究
3. Mesoporous cross-linked polymer copolymerized with chiral BINAP ligand coordinated to a ruthenium species as an efficient heterogeneous catalyst for asymmetric hydrogenation [J] . Qi Sun, Xiangju Meng, Xiao Liu, Chemical Communications . 2012,第85期

机译：与手性BINAP配体共聚的介孔交联聚合物与钌物种配位，可作为不对称氢化的高效多相催化剂
4. Reaction Characteristics of Immobilized Ru-BINAP Catalysts in Asymmetric Hydrogenation of Dimethyl itaconate [C] . Sung Hyun Ahn, Yeung Ho Park, Pierre A. Jacobs Asia-Pacific Chemical Reaction Engineering Symposium(APCRE'05); 20050612-15; Gyeongju(KR) . 2005

机译：固定化Ru-BINAP催化剂在衣康酸二甲酯不对称加氢中的反应特性
5. 1. Reduction of Tertiary Benzamides to Benzaldehydes by an in situ-Generated Schwartz Reagent (Cp2 Zirconium (Hydrogen)Chloride); Formal Synthesis of Lysergic Acid. 2. Ru-Catalyzed Amide-Directed Aryl Carbon-Hydrogen, Carbon-Nitrogen and Carbon-Oxygen Bond Functionalizations: C-B Formation, Carbon-Carbon Suzuki Cross Coupling and Hydrodemethoxylation [D] . Zhao, Yigang 2011

机译：1.通过原位生成的Schwartz试剂（Cp2氯化锆（氢）氯化物）将叔苄酰胺还原为苯甲醛；麦角酸的正式合成。 2. Ru催化的酰胺基芳烃碳氢，碳氮和碳氧键功能化：C-B形成，碳-碳铃木交叉偶联和加氢脱甲氧基化
6. Asymmetric transfer hydrogenation of imines and ketones using chiral Ru(II)Cl(η6-p-cymene)(SS)-N-TsDPEN catalyst: a computational study [O] . Petr Kačer, Jiří Václavík, Jan Přech, 2012

机译：使用手性Ru（II）Cl（η6-对-异丙基）（SS）-N-TsDPEN催化剂进行亚胺和酮的不对称转移氢化：一个计算研究
7. Synthesis, characterization and application of Ru(BINAP)(Acac)(MNAA)(MeOH), a highly effective catalyst for the asymmetric hydrogenation of 2-(6′-methoxynaphth-2′-yl)acrylic acid [O] . Chen CC, Huang TT, Lin CW, 1998

机译：Ru（BINAP）（Acac）（MNAA）（MeOH）的合成，表征和应用-一种高效的2-（6'-甲氧基萘-2'-基）丙烯酸不对称加氢催化剂

Ru coordinated with BINAP in knitting aryl network polymers for heterogeneous asymmetric hydrogenation of methyl acetoacetate

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