Reaction of α-amido sulfones with functionalized nitrocompounds: a new two-step synthesis of N-alkoxycarbonyl-2,5-disubstituted pyrroles

Roberto Ballini; Serena Gabrielli; Alessandro Palmieri; Marino Petrini

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Reaction of α-amido sulfones with functionalized nitrocompounds: a new two-step synthesis of N-alkoxycarbonyl-2,5-disubstituted pyrroles

机译：α-氨基砜与官能化氮化合物的反应：N-烷氧基羰基-2,5-二取代的胃果的新两步合成

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Reaction of α-amido sulfones with nitro ketals promoted by KF on alumina provides the corresponding adducts which, upon treatment with p -toluenesulfonic acid, generate the corresponding N -alkoxycarbonyl-2,5-disubstituted pyrroles. The latter transformation involves a cascade process including ketal cleavage, ring closure and final aromatization by nitrous acid elimination.

机译：α-氨基砜与KF促进氧化铝促进的硝基的反应提供了相应的加合物，该加合物在用磷酸盐处理后处理，产生相应的N-烷氧基羰基-2,5-二取代的吡咯。后一种转化涉及通过亚硝酸消除，包括缩乳裂解，环闭合和最终芳族化。

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《RSC Advances》 |2014年第81期|共4页
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Roberto Ballini; Serena Gabrielli; Alessandro Palmieri; Marino Petrini;
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1. Reaction of alpha-amido sulfones with functionalized nitrocompounds: a new two-step synthesis of N-alkoxycarbonyl-2,5-disubstituted pyrroles [J] . Ballini Roberto, Gabrielli Serena, Palmieri Alessandro, RSC Advances . 2014,第81期

机译：α-酰胺基砜与官能化硝基化合物的反应：N-烷氧基羰基-2,5-二取代吡咯的新两步合成方法
2. Simple two-step synthesis of 2,4-disubstituted pyrroles and 3,5-disubstituted pyrrole-2-carbonitriles from enones [J] . Murat Kucukdisli, Dorota Ferenc, Marcel Heinz, Beilstein journal of organic chemistry. . 2014,第1期

机译：由烯酮简单地分两步合成2,4-二取代的吡咯和3,5-二取代的吡咯-2-腈
3. Regioselective Synthesis of 2,5-Disubstituted Pyrroles via Stepwise Iododesilylation and Coupling Reactions [J] . Yu Qixin, Li Xiaoyu, Wang Xinyue, Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry . 2018,第2a3期

机译：通过逐步碘化物和偶联反应的2,5-二取代的辐注的区域选择性合成
4. Identification of the Protonated Sulfone and Carboxylic Acid Functionalities by Using Ion-Molecule Reactions Followed by Collision-Induced Dissociation in a Linear Quadrupole Ion Trap Mass Spectrometer [C] . Ravikiran Yerabolu, John Kong, Mckay Easton, ASMS Conference on Mass Spectrometry and Allied Topics . 2015

机译：通过使用离子分子反应鉴定质子化砜和羧酸官能团，然后在线性四极离子阱质谱仪中进行碰撞诱导的解离
5. Design and synthesis of ligands based on trans-2,5-disubstituted pyrrolidines and their application in asymmetric catalytic reactions. [D] . Chen, Hongfeng. 2002

机译：基于反式2,5-二取代吡咯烷的配体的设计与合成及其在不对称催化反应中的应用。
6. Simple two-step synthesis of 24-disubstituted pyrroles and 35-disubstituted pyrrole-2-carbonitriles from enones [O] . Murat Kucukdisli, Dorota Ferenc, Marcel Heinz, 2014

机译：由烯酮简单地两步合成24-二取代吡咯和35-二取代吡咯-2-腈
7. Simple two-step synthesis of 2,4-disubstituted pyrroles and 3,5-disubstituted pyrrole-2-carbonitriles from enones [O] . Murat Kucukdisli, Dorota Ferenc, Marcel Heinz, 2014

机译：从烯酮中简单地两步合成2,4-二取代吡咯和3,5-二取代吡咯-2-碳腈

Reaction of α-amido sulfones with functionalized nitrocompounds: a new two-step synthesis of N-alkoxycarbonyl-2,5-disubstituted pyrroles

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