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Methyl Acrylate Derivatives as Corrosion Inhibitors for X-65 Type Carbon Steel in 1 M HCl

机译:丙烯酸甲酯衍生物作为X-65型碳钢的腐蚀抑制剂在1M HCl中

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Inhibition efficiency of prepared Methyl acrylate derivatives named 2- Methacryloyloxyethyloctadecyldimethylammonium Bromide (MEODAB), poly(2- Methacryloyloxyethyloctadecyldimethylammonium Bromide) (PMEODAB) for X-65 type carbon steel in 1 M HCl has been investigated by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The prepared acrylate derivatives act as mixed-type inhibitors, which suppresses both cathodic and anodic processes by its adsorption on the electrode surface according to Langmuir adsorption isotherm, together with a slight positive shift in corrosion potential (Ecorr). The inhibition efficiency IE% reached 89.3% for compound (MEODAB) and 88.1 % for compound (PMEODAB) at 150 ppm. The data obtained from electrochemical impedance spectroscopy (EIS) was analyzed to model the corrosion inhibition process through equivalent circuit. The nature of the protecting film formed on carbon steel was investigated by SEM and EDX techniques.
机译:通过电位极化和电化学阻抗光谱(EIS)研究了X-65型碳钢的制备甲基丙烯酸甲酯衍生物的制备甲基丙烯酸甲酯衍生物的抑制效率已经研究了X-65型碳钢的聚(2-甲基丙烯酰氧基乙基溴铵)(PMeodab) 测量。 制备的丙烯酸酯衍生物充当混合型抑制剂,其通过根据Langmuir吸附等温线的吸附来抑制阴极和阳极工艺,以及腐蚀电位(Ecorr)的轻微正换量。 抑制效率IE%在150ppm下为化合物(Meodab)和88.1%的化合物(PMeodab)达到89.3%。 分析了从电化学阻抗光谱(EIS)获得的数据以通过等效电路模拟腐蚀抑制过程。 通过SEM和EDX技术研究了在碳钢上形成的保护膜的性质。

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