Abstract UV-filters and musk fragrances in seafood commercialized in Europe Union: Occurrence, risk and exposure assessment
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UV-filters and musk fragrances in seafood commercialized in Europe Union: Occurrence, risk and exposure assessment

机译：在欧盟商业化的海鲜中的紫外线过滤剂和麝香香料：发生，风险和暴露评估

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摘要

AbstractIn the framework of the FP7 ECsafeSeafood project, 62 seafood samples commercialized in Europe Union from several representative species – mackerel, tuna, salmon, seabream, cod, monkfish, crab, shrimp, octopus, perch and plaice – were analysed for residues of 21 personal care products (PCPs), including 11 UV-filters (UV-Fs) and 10 musk fragrances (musks). PCPs analysis were performed by Quick, Easy, Cheap, Effective Rugged, Safe (QuEChERS), combined with liquid-liquid extraction (LLE) or dispersive solid-phase extraction (dSPE), followed by gas chromatography-tandem mass spectrometry (GC-MS/MS). The results showed the presence in a wide range of samples of nine out of eleven UV-Fs compounds analysed, namely 2-ethylhexyl salicylate (EHS), 2-ethylhexyl,4-methoxycinnamate (EHMC), 4-methylbenzylidenecamphor (4-MBC), benzophenone-1 (BP1), benzophenone-3 (BP3), isoamyl-4-methoxycinnamate (IMC), 2,2′-dihydroxy-4,4′-dimethoxybenzophenone (DHMB), homosalate (HS), and octocrylene (OC), whereas galaxolide (HHCB), galaxolide lactone (HHCB-lactone), and tonalide (AHTN) were the most found musks. The potential risks to human health associated with the exposure to eight of the more prevalent PCPs – EHS, EHMC, 4-MBC, BP1, BP3, IMC, HHCB, and AHTN - through seafood consumption were assessed for consumers from five European countries (Belgium, Ireland, Italy, Portugal and Spain). Results showed that the human exposure to UV-Fs and musks estimated from the concentration values found in seafood and the daily consumption of concerned seafood species, were far below toxicological reference values.Graphical abstractDisplay OmittedHighlights•Largest survey on UV-Fs and musks in seafood commercialized in Europe.•Farmed seabream showed the highest average concentration of UV-Fs.•Wild mackerel showed the highest average concentration of polycyclic musks.•UV-Fs and musks in raw samples were far below the estimated toxicological reference value.
机译： 摘要 在FP7 ECsafeSeafood项目的框架内，在欧盟商业化的62种海鲜样品来自几种代表性物种：鲭鱼，金枪鱼，鲑鱼，鲷鱼，鳕鱼，安康鱼，螃蟹，分析了虾，章鱼，鲈鱼和的21种个人护理产品（PCP）的残留，其中包括11种紫外线过滤剂（UV-Fs）和10种麝香香精（麝香）。 PCP分析通过快速，简便，廉价，有效耐用，安全（QuEChERS）进行，结合液-液萃取（LLE）或分散固相萃取（dSPE），然后进行气相色谱-串联质谱（GC-MS） /多发性硬化症）。结果表明，在分析的11种UV-Fs化合物中，有9种存在多种样品，分别是水杨酸2-乙基己酯（EHS），2-乙基己基，4-甲氧基肉桂酸酯（EHMC），4-甲基亚苄基樟脑（4-MBC） ，二苯甲酮1（BP1），二苯甲酮3（BP3），-4-甲氧基肉桂酸异戊酯（IMC），2,2'-二羟基-4,4'-二甲氧基二苯甲酮（DHMB），高粘酸盐（HS）和辛二烯（OC ），而加拉索利德（HHCB），加拉索利德内酯（HHCB-内酯）和tonalide（AHTN）是发现最多的麝香。针对来自五个欧洲国家（比利时）的消费者，评估了他们通过食用海鲜而接触到的八个更普遍的五氯苯酚（EHS，EHMC，4-MBC，BP1，BP3，IMC，HHCB和AHTN）对人体健康的潜在风险。 ，爱尔兰，意大利，葡萄牙和西班牙）。结果表明，从海鲜中的浓度值和相关海鲜种类的日摄入量估算得出的人类暴露于UV-Fs和麝香的程度远低于毒理学参考值。 图形摘要 省略显示 突出显示 • 啦关于在欧洲商业化的海鲜中UV-Fs和麝香的简要调查。 • 养殖鲷鱼的UV-Fs平均浓度最高。 • 野生鲭鱼的多环麝香平均浓度最高。 < / ce：list-item> • UV-Fs和原始样品中的麝香远低于估计的毒理学参考值。 < / ce：抽象>

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  • 来源
    《Environmental research》 |2018年第2期|399-408|共10页
  • 作者

    S.C. Cunha; L. Trabalón; S. Jacobs; M. Castro; M. Fernandez-Tejedor; K. Granby; W. Verbeke; C. Kwadijk; F. Ferrari; J. Robbens; I. Sioen; E. Pocurull; A. Marques; J.O. Fernandes; J.L. Domingo;

  • 作者单位

    LAQV-Requimte, Laboratory of Bromatology and Hydrology, Faculty of Pharmacy, University of Porto;

    Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili;

    Department of Public Health, Ghent University,Department of Agricultural Economics, Ghent University;

    LAQV-Requimte, Laboratory of Bromatology and Hydrology, Faculty of Pharmacy, University of Porto;

    Institute of Agrifood Research and Technology (IRTA);

    Technical University of Denmark, National Food Institute;

    Department of Agricultural Economics, Ghent University;

    Institute for Marine Resources and Ecosystem Studies (IMARES);

    Aeiforia Srl;

    Institute for Agricultural and Fisheries Research (ILVO), Animal Sciences Unit – Fisheries;

    Department of Public Health, Ghent University,Department of Food Safety and Food Quality, Ghent University;

    Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira i Virgili;

    Portuguese Institute for the Sea and Atmosphere, I.P. (IPMA),Interdisciplinary Centre of Marine and Environmental Research (CIIMAR);

    LAQV-Requimte, Laboratory of Bromatology and Hydrology, Faculty of Pharmacy, University of Porto;

    Laboratory of Toxicology and Environmental Health, School of Medicine, IISPV, Universitat Rovira i Virgili;

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  • 正文语种 eng
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  • 关键词

    Fish; UV-filters; Musk fragrances; Occurrence; Risk assessment; GC-MS/MS;

    机译：鱼;紫外线过滤器;麝香;发生;风险评估;GC-MS / MS;

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