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Surface-Enhanced Raman Spectroscopy: A Facile and Rapid Method for the Chemical Component Study of Individual Atmospheric Aerosol

机译:表面增强拉曼光谱:一种简便快速的方法,用于研究单个大气气溶胶的化学成分

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摘要

A simple and rapid method for detecting chemical components of individual aerosol particles on Klarite substrate with surface-enhanced Raman spectroscopy (SERS) is described. For both single simulated aerosol particles and ambient atmospheric particles, this new analytical method promotes the enhancement factor of the Raman signal. The spectra of ammonium sulfate and naphthalene particles at the microscopic level are enhanced by a factor of 6 and therefore greatly improve the detection of the chemical composition of an individual aerosol particle. When aerosol particles are found over a microscopic domain, a set of Raman spectra with chemical information can be obtained via SERS mapping. The maps illustrate the distribution of organic or inorganic species on the SERS substrate. This constitutes a facile and rapid method to study aerosol particles. This new method allows the analysis of chemical composition in single aerosol particles, demonstrating the power of SERS to probe the ambient atmospheric particles and to study the formation of aerosol particles.
机译:描述了一种利用表面增强拉曼光谱(SERS)检测Klarite基质上单个气溶胶颗粒化学成分的简单快速方法。对于单个模拟的气溶胶颗粒和周围的大气颗粒,这种新的分析方法都可以提高拉曼信号的增强因子。微观水平的硫酸铵和萘颗粒的光谱增强了6倍,因此大大改善了单个气雾剂颗粒化学成分的检测。当在微观区域发现气溶胶颗粒时,可以通过SERS映射获得一组具有化学信息的拉曼光谱。这些图说明了SERS基底上有机或无机物质的分布。这是研究气溶胶颗粒的便捷方法。这种新方法可以分析单个气溶胶颗粒中的化学成分,从而证明SERS能够探测周围的大气颗粒并研究气溶胶颗粒的形成。

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  • 来源
    《Environmental Science & Technology》 |2017年第11期|6260-6267|共8页
  • 作者单位

    Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science & Engineering,Fudan University, Shanghai 200433, People's Republic of China;

    Centre for Photonics and Photonic Materials, Department of Physics, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom;

    Centre for Photonics and Photonic Materials, Department of Physics, University of Bath, Claverton Down, Bath BA2 7AY, United Kingdom;

    Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science & Engineering,Fudan University, Shanghai 200433, People's Republic of China;

    Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science & Engineering,Fudan University, Shanghai 200433, People's Republic of China;

    Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science & Engineering,Fudan University, Shanghai 200433, People's Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
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