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Behavior of mercury emitted from the combustion of coal and dried sewage sludge: The effect of unburned carbon, Cl, Cu and Fe

机译:煤和干污泥燃烧产生的汞排放行为:未燃烧的碳,Cl,Cu和Fe的影响

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摘要

As the behavior of mercury generated from the combustion of mercury-containing fuels is highly dependent upon mercury speciation, many studies have investigated mercury speciation following combustion of various fuels. Unburned carbon and the content of chlorine (Cl), copper (Cu), and iron (Fe) compounds in ash are reported to affect the behavior of mercury. This study was conducted to understand the important factors impacting behavior of mercury from single coal combustion and co-combustion of dried sewage sludge with coal. Factors reported in previous studies were selected as potential factors affecting mercury oxidation and retention. Six coal and six dried sewage sludge samples were used to conduct single coal combustion and co-combustion tests. Each fuel sample was combusted in a lab-scale drop tube combustion system. Concentrations of elemental and oxidized mercury were determined using the Ontario Hydro Method. Ash samples collected on the bottom of the combustion system were analyzed to determine unburned carbon and mercury retention percentages. Unburned carbon and Cl were found to be important in both oxidation and retention of mercury for single coal combustion. Cl, Cu, and Fe content increased the oxidation of elemental mercury generated from co-combustion of dried sewage sludge with coal. (C) 2017 Elsevier Ltd. All rights reserved.
机译:由于含汞燃料燃烧产生的汞行为高度依赖于汞的形态形成,因此许多研究已经研究了各种燃料燃烧后的汞形态。据报告,灰中未燃烧的碳以及氯(Cl),铜(Cu)和铁(Fe)化合物的含量会影响汞的行为。进行这项研究是为了了解影响单一煤燃烧以及干污泥与煤共燃烧中汞行为的重要因素。选择先前研究中报道的因素作为影响汞氧化和保留的潜在因素。使用六个煤和六个干燥污水污泥样品进行了一次煤燃烧和混合燃烧测试。每个燃料样品都在实验室规模的下管燃烧系统中燃烧。使用安大略水电法测定元素汞和氧化汞的浓度。分析在燃烧系统底部收集的灰分样品,以确定未燃烧的碳和汞保留百分比。发现未燃烧的碳和Cl对于单一煤燃烧在汞的氧化和保留方面都非常重要。 Cl,Cu和Fe的含量增加了干污泥与煤共燃烧产生的元素汞的氧化。 (C)2017 Elsevier Ltd.保留所有权利。

著录项

  • 来源
    《Fuel》 |2017年第1期|749-756|共8页
  • 作者

    Lee Sang-Sup; Wilcox Jennifer;

  • 作者单位

    Chungbuk Natl Univ, Dept Environm Engn, Cheongju 28644, South Korea;

    Colorado Sch Mines, Dept Chem & Biol Engn, Golden, CO 80401 USA;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Coal; Dried sewage sludge; Mercury; Combustion;

    机译:煤炭;干污泥;汞;燃烧;

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