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Hydrogen absorption/desorption characteristics of Mg-V-Ni hydrogen storage alloys

机译:Mg-V-Ni贮氢合金的氢吸收/解吸特性

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In this study, Mg + 5at%V + 5at%Ni alloys are prepared by wet mechanical alloying (MA) in an organic solvent under a purified argon atmosphere. The hydrogen absorption capacities of the samples are evaluated at 473 K at an initial hydrogen pressure of 0.2 MPa in a Sieverts apparatus. First, to obtain the ideal hydrogen absorption and desorption characteristics, organic solvents for milling are changed. Among the alloy samples milled with different organic solvents, the maximum hydrogen absorption capacity is obtained for the alloy prepared with benzene. After determining the organic solvent, the milling time was varied from 3 to 8 h. The maximum hydrogen absorption capacity of 5.15 mass% can be achieved in 7 h-milling. Furthermore, the apparent hydrogen diffusion coefficients are obtained by fitting the temporal change of the hydrogen absorption capacity with a theoretical curve. The theoretical curves are calculated, assuming that the particle shape is a sphere and the size of the sample is 40 mu m.
机译:在这项研究中,Mg + 5at%V + 5at%Ni合金是通过在纯氩气氛下在有机溶剂中进行湿式机械合金化(MA)制备的。在Sieverts装置中,在初始氢气压力为0.2MPa的情况下,在473K下评估样品的氢吸收容量。首先,为了获得理想的氢吸收和解吸特性,改变了用于研磨的有机溶剂。在用不同有机溶剂研磨的合金样品中,苯制得的合金具有最大的氢吸收能力。确定有机溶剂后,研磨时间从3到8小时不等。在7小时的研磨中可以达到5.15质量%的最大氢吸收容量。此外,通过将氢吸收容量的时间变化与理论曲线拟合来获得表观氢扩散系数。假设颗粒形状为球形且样品尺寸为40μm,则计算理论曲线。

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