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Optical and AC conductivity studies of Co doped TiO_2 nanotubes

机译:Co掺杂TiO_2纳米管的光学和交流电导率研究

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摘要

Cobalt doped TiO_2 nanotubes are prepared by the combination of sol-gel process with hydrothermal treatment. The morphology and crystalline structure of TiO_2 nanotubes are characterised by transmission electron microscopy (TEM) and X-ray diffraction respectively. Optical studies are done by UV-Vis reflectance spectra and photoluminescence spectra (PL). Co doping induces a structural transformation from anatase to rutile. PL spectrum shows the presence of surface oxygen vacancies and self trapped excitons in Co doped and undoped TiO_2 nanotubes. Co doped sample show a peak in PL spectrum at 526 nm, which is not in the undoped sample. An AC conductivity data analysis is carried out in the temperature range 303 to 423 K for the TiO_2 nanotubes and Co doped TiO_2 nanotubes. The temperature at which the transition to the positive temperature coefficient of resistance occurs differs in undoped and Co doped TiO_2 nanotubes.
机译:溶胶-凝胶法与水热处理相结合制备了钴掺杂的TiO_2纳米管。分别通过透射电子显微镜(TEM)和X射线衍射表征了TiO_2纳米管的形貌和晶体结构。光学研究是通过UV-Vis反射光谱和光致发光光谱(PL)进行的。共掺杂诱导从锐钛矿到金红石的结构转变。 PL光谱显示在Co掺杂和未掺杂的TiO_2纳米管中存在表面氧空位和自陷激子。共掺杂样品在526 nm的PL光谱中显示出一个峰,未掺杂样品中没有。对于TiO_2纳米管和Co掺杂的TiO_2纳米管,在303至423K的温度范围内进行AC电导率数据分析。在未掺杂和Co掺杂的TiO_2纳米管中,发生向电阻正温度系数转变的温度不同。

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