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Nonlinear polarization responses of ZrO_2-based thin films fabricated by chemical solution deposition

机译:化学溶液沉积法制备ZrO_2基薄膜的非线性极化响应

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摘要

The nonlinear polarization responses of ZrO2-based thin films were investigated. Y, Ce, Ti, and Sn were used as substitutes in ZrO2 thin films by chemical solution deposition. A pure ZrO2 film and the ZrO2 film with 1% Y substitution showed constricted polarization-electric field (P-E) curves. In contrast, the ZrO2 film with 5% Y substitution showed a linear P-E curve. The dielectric constants of the pure ZrO2 film and the ZrO2 film with 1% Y substitution increased by 7 and 11%, respectively, under an applied electric field of 2.5 MV/cm. The nonlinearity of the polarization responses was decreased by Ce substitution and Ti substitution. The ZrO2 films with Sn substitution showed narrow P-E curves. The dielectric constant of the ZrO2 film with 10% Sn substitution increased by 13% under an applied electric field of 3 MV/cm. These dielectric constant increases originate from electric-field-induced phase transitions of ZrO2-based thin films. (C) 2017 The Japan Society of Applied Physics
机译:研究了ZrO2基薄膜的非线性极化响应。通过化学溶液沉积法,将Y,Ce,Ti和Sn用作ZrO2薄膜的替代物。纯ZrO2膜和1%Y取代的ZrO2膜显示出狭窄的极化电场(P-E)曲线。相比之下,Y取代度为5%的ZrO2膜显示线性P-E曲线。在2.5 MV / cm的施加电场下,纯ZrO2膜和ZrO2膜(具有1%的Y取代)的介电常数分别增加了7%和11%。 Ce替换和Ti替换降低了偏振响应的非线性。锡取代的ZrO2薄膜显示出窄的P-E曲线。在3 MV / cm的施加电场下,具有10%锡取代的ZrO2薄膜的介电常数提高了13%。这些介电常数的增加源自电场引起的基于ZrO2的薄膜的相变。 (C)2017日本应用物理学会

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