...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Journal of Applied Physics >Qualitative analysis of a diamondlike carbon film by angle-resolved x-ray photoelectron spectroscopy
【24h】

Qualitative analysis of a diamondlike carbon film by angle-resolved x-ray photoelectron spectroscopy

机译：用角分辨X射线光电子能谱对类金刚石碳膜进行定性分析

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Angle-resolved x-ray photoelectron spectroscopy was used to investigate the surface of a diamondlike carbon film prepared by the ionized deposition method. We then analyzed the C 1s spectra using the Doniach-Sunjic (DS) [J. Phys. C 3, 285 (1970)] function convoluted with a Gaussian function. Consequently, we obtained four fitting curves for the carbon components in each spectrum, regardless of the assumption of the singularity index (α) in the DS function, which expresses the asymmetry of the C 1s spectrum. The curves were assigned in the order of binding energy to bulk sp~3 carbon (283.7-283.8 eV), bulk sp~2 carbon (284.2-284.3 eV), surface sp~2 carbon (284.7-284.8 eV), and surface sp~3 (285.3-285.4 eV) carbon. We further considered the influence of the assumption of α. Consequently, we suggest that the C 1s spectra can be quantitatively analyzed without considering the influences of a when the ratio of α for sp~2 carbon to that for sp~3 carbon [α(sp~2): α(sp~3)] is between 10:0 and 5:5. The distribution in the α ratio may indicate that the sp~2 and the sp~3 carbon atoms can interact with each other (hybridization) and differ from those highly oriented pyrolytic graphite and diamond, respectively.
机译：用角分辨X射线光电子能谱研究通过电离沉积法制备的类金刚石碳膜的表面。然后，我们使用Doniach-Sunjic（DS）分析了C 1s光谱[J.物理C 3，285（1970）]函数与高斯函数卷积。因此，无论在DS函数中假设奇异性指数（α）表示C 1s光谱的不对称性如何，我们都获得了四个光谱中碳组分的拟合曲线。曲线按结合能的顺序分配给本体sp〜3碳（283.7-283.8 eV），本体sp〜2碳（284.2-284.3 eV），表面sp〜2碳（284.7-284.8 eV）和表面sp 〜3（285.3-285.4 eV）碳。我们进一步考虑了α假设的影响。因此，我们建议当sp〜2碳的α与sp〜3碳的α之比[α（sp〜2）：α（sp〜3）]时，可以不考虑a的影响而定量分析C 1s光谱。 ]在10：0和5：5之间。 α比率的分布可能表明sp〜2和sp〜3碳原子可以彼此相互作用（杂化），并且分别不同于那些高度取向的热解石墨和金刚石。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号