Crystal growth, structural, thermal, optical and laser damage threshold studies of 8-hydroxyquinolinium hydrogen maleate single crystals

G. Peramaiyan; P. Pandi; N. Vijayan; G. Bhagavannarayana; R. Mohan Kumar

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Crystal growth, structural, thermal, optical and laser damage threshold studies of 8-hydroxyquinolinium hydrogen maleate single crystals

机译：8-羟基喹啉马来酸氢盐单晶的晶体生长，结构，热，光学和激光损伤阈值研究

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Organic nonlinear optical crystal, 8-hydroxyquinolinium hydrogen maleate (8-HQM) with a dimension of 30 × 4 × 4 mm~3 was grown by the slow evaporation solution growth technique. The cell parameters of grown crystal were confirmed by single crystal X-ray diffraction analysis and it belongs to the noncentrosymmetric space group P2_12_12_1. The crystalline perfection of 8-HQM crystal was examined by high resolution X-ray diffraction studies. UV-vis transmittance studies confirm the optical transparency window in the (480-900 nm) region. The TGA/DTA thermal measurements reveal that 8-HQM is thermally stable up to 160 ℃. The laser damage threshold value of 8-HQM crystal was estimated to be 1.2 GW/cm~2 using a Nd:YAG laser. The relative second harmonic generation efficiency of 8-HQM crystal was found to be seven times greater than that of KDP.

机译：通过缓慢蒸发溶液生长技术，生长了尺寸为30×4×4mm〜3的有机非线性光学晶体马来酸8-羟基喹啉氢（8-HQM）。通过单晶X射线衍射分析确定了生长晶体的晶胞参数，它属于非中心对称空间群P2_12_12_1。通过高分辨率X射线衍射研究检查了8-HQM晶体的晶体完整性。紫外可见透射率研究证实了（480-900 nm）区域的光学透明性。 TGA / DTA的热测量结果表明8-HQM在高达160℃的温度下具有热稳定性。使用Nd：YAG激光估计8-HQM晶体的激光损伤阈值为1.2 GW / cm〜2。发现8-HQM晶体的相对二次谐波产生效率是KDP的相对七倍。

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来源
《Journal of Crystal Growth》 |2013年第15期|6-9|共4页
作者
G. Peramaiyan; P. Pandi; N. Vijayan; G. Bhagavannarayana; R. Mohan Kumar;
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作者单位

Department of Physics, Presidency College, Chennai 600005, India;

Department of Physics, Presidency College, Chennai 600005, India ,Department of Physics, Panimalar Engineering College, Chennai 600123, India;

Materials Characterization Division, National Physical Laboratory, New Delhi 110012, India;

Materials Characterization Division, National Physical Laboratory, New Delhi 110012, India;

Department of Physics, Presidency College, Chennai 600005, India;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 afa
中图分类
关键词
A1. Solubility; A2. Growth from solutions; B1. Organic compounds; B2. Nonlinear optical material; B2. Second harmonic generation;

机译：A1。溶解度;A2。解决方案的增长;B1。有机化合物;B2。非线性光学材料;B2。二次谐波的产生;

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Crystal growth, structural, thermal, optical and laser damage threshold studies of 8-hydroxyquinolinium hydrogen maleate single crystals

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