PREPARATION AND CRYSTAL STRUCTURE OF GUANIDINIUM CYCLODODECAPHOSPHATE HEXAHYDRATE - [C(NH2)(3)]12P12O36-CENTER-DOT-6H(2)O

Schulke U.; Averbuchpouchot MT.

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PREPARATION AND CRYSTAL STRUCTURE OF GUANIDINIUM CYCLODODECAPHOSPHATE HEXAHYDRATE - [C(NH2)(3)]12P12O36-CENTER-DOT-6H(2)O

机译：环十二碳六环合钒酸盐的制备和晶体结构-[C（NH2）（3）] 12P12O36-CENTER-DOT-6H（2）O

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The title compound was prepared by ion exchange from the potassium salt, K12P12O36. 19/2H(2)O. It represents a second new structural type of [P12O36](12-) ring anions. This sparingly water soluble salt is hexagonal, space group P6(3), with Z=2 and the cell dimensions: a=15.904(7), c=16.67(2) Angstrom. The crystal structure was solved by direct methods and refined to a final R value of 0.050. The ring anion is located around the threefold axis and hence has a threefold symmetry. The stacking of the rings creates large channels, parallel to the c direction, in which the guanidinium groups and the water molecules are located. Three of the six independent guanidinium groups are located on the threefold axes. The cohesion of the structure is performed by the numerous H-bonds generated by the organic cations and the water molecules. [References: 8]

机译：通过从钾盐K12P12O36进行离子交换来制备标题化合物。 19 / 2H（2）O。它代表了[P12O36]（12-）环阴离子的第二种新结构类型。这种微溶于水的盐是六边形的，空间群P6（3），Z = 2，像元尺寸为：a = 15.904（7），c = 16.67（2）埃。通过直接方法解析晶体结构，并将其精制至最终R值为0.050。环状阴离子位于三重轴周围，因此具有三重对称性。环的堆叠形成平行于c方向的大通道，胍基和水分子位于该通道中。六个独立胍基组中的三个位于三重轴上。结构的凝聚力是由有机阳离子和水分子产生的大量H键实现的。 [参考：8]

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来源
《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1995年第7期|p. 1232-1236|共5页
作者
Schulke U.; Averbuchpouchot MT.;
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UNIV GRENOBLE 1 CRISTALLOG LAB CNRS BP 166X F-38042 GRENOBLE 09 FRANCE;

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正文语种 eng
中图分类化学;
关键词
Guanidinium cyclododecaphosphate hexahydrate; Preparation; Crystal structure; Phosphate-ring anion;

机译：六水合环十二磷酸胍盐;制备;晶体结构;磷酸环阴离子;

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1. PREPARATION AND CRYSTAL STRUCTURE OF GUANIDINIUM CYCLODODECAPHOSPHATE TELLURIC ACID HYDRATE - [C(NH2)(3)]12P12O36-CENTER-DOT-12TE(OH)(6)CENTER-DOT-24H(2)O [J] . Averbuchpouchot MT., Schulke U. Zeitschrift fur Anorganische und Allgemeine Chemie . 1996,第11期

机译：环癸二酸碲酸水合物的制备及晶体结构-[C（NH2）（3）] 12P12O36-CENTER-DOT-12TE（OH）（6）CENTER-DOT-24H（2）O
2. Calculation of the band structure and optical properties of guanidinium aluminum sulfate hexahydrate crystals [J] . Andriyevsky B.V., Romanyuk N.A., Romanyuk N.N., Physics of the solid state . 2012,第10期

机译：六水合硫酸铝胍晶体的能带结构和光学性质的计算
3. The structure-directing influence of guanidinium cations in the crystal structures of [C(NH2)(3)](2)[M-II(H2O)(4)(VO3)(4)] center dot 4H(2)O (M = Mn, Co, Ni) [J] . Abrahams BF, Haywood MG, Robson R Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第26期

机译：胍盐阳离子对[C（NH2）（3）]（2）[M-II（H2O）（4）（VO3）（4）]中心点4H（2）O（）的晶体结构的影响M = Mn，Co，Ni）
4. Investigations on growth, structure, optical properties and laser damage threshold of organic nonlinear optical crystals of Guanidinium L-Ascorbate [C] . Ravi Kiran Saripalli, Sanath Kumar, H. L. Bhat, Conference on Nonlinear Optics and Applications IX . 2015

机译：L-抗坏血酸有机非线性光学晶体的生长，结构，光学性质和激光损伤阈值的研究
5. THE CRYSTAL STRUCTURE DETERMINATIONS OF PENTAMERIC CUPRIC-CHLORIDE DI-ISOPROPANOL, DYSPROSIUM-CHLORIDE HEXAHYDRATE AND SILVER PERCHLORATE 4L(L = 4-METHYL-3,5,8-TRIUXA-1-PHOSPHA-BICYCLO(2.2.2)OCTANE). [D] . URGO, JOSEF VENDAL, JR. 1967

机译：戊二酸氯化铜-二异异丙醇，氯化亚磷酸氢铵和高氯酸银4L（L = 4-甲基-3,5,8-TRIUXA-1-PHOSPHA-BICYCLO（2.2.2）辛酸）的晶体结构测定。
6. Crystal structures of the three closely related compounds: bis(1H-tetrazol-5-yl)methylnitramide triaminoguanidinium 5-({(1H-tetrazol-5-yl)methyl(nitro)amino}methyl)tetrazol-1-ide and diammonium bis(tetrazol-1-id-5-yl)methylnitramide monohydrate [O] . Lauren A. Mitchell, Gregory H. Imler, Damon A. Parrish, 2017

机译：三种密切相关的化合物的晶体结构：双（（1H-四唑-5-基）甲基硝酰胺三氨基胍鎓5-（{（（1H-四唑-5-基）甲基（硝基）氨基}甲基）四唑- 1-ide和二双（（四唑-1-基-5-基）甲基硝酰胺一水合二铵
7. Citrate, in Collaboration with a Guanidinium Ion, as a Generator of Cubane-like Complexes with a Range of Metal Cations: Synthesis, Structures, and Magnetic Properties of C(NH2)38(MII)4(cit)48H2O (M = Mg, Mn, Fe, Co, Ni, and Zn; cit = Citrate) [O] . -1

机译：柠檬酸盐与胍鎓离子合作，作为具有一系列金属阳离子的Cubane样复合物的发电机：C（NH2）3 8 （MII）4（CIT）4的合成，结构和磁性，4 8H2O（M = Mg，Mn，Fe，Co，Ni和Zn; Cit =柠檬酸盐）
8. Refinement of the Crystal Structure of Guanidinium Aluminum Sulfate Hexahydrate [R] . Schein, B. J. B. 1966

机译：六水合硫酸胍六水合物晶体结构的细化

PREPARATION AND CRYSTAL STRUCTURE OF GUANIDINIUM CYCLODODECAPHOSPHATE HEXAHYDRATE - [C(NH2)(3)]12P12O36-CENTER-DOT-6H(2)O

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