首页> 外文期刊>Zeitschrift fur Naturforschung. A, A journal of physical sciences >The ~(33)S Nuclear Quadrupole Coupling in the Rotational Spectrum of 2,2-Dimethylthiirane
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The ~(33)S Nuclear Quadrupole Coupling in the Rotational Spectrum of 2,2-Dimethylthiirane

机译:2,2-二甲基硫代硅烷旋转光谱中的〜(33)S核四极偶合

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摘要

The rotational spectrum of ~(33)S 2,2-dimethylthiirane with its ~(33)S nuclear quadrupole coupling hyperfine structure in the range 8.9 to 20.0 GHz and its analysis is reported. The rotational constants are A = 5507.4663(3), B = 3440.58395(18), and C = 2978.5723(3) MHz. The ~(33)S quadrupole coupling constants are χ_(aa) = -22.6390(23), χ_(bb) = 47.1830(50), and χ_(cc) = -24.5440(50) MHz.
机译:报道了〜(33)S 2,2-二甲基硫杂环戊烷及其〜(33)S核四极偶合超精细结构的旋转光谱,并对其进行了分析。旋转常数为A = 5507.4663(3),B = 3440.58395(18)和C = 2978.5723(3)MHz。 〜(33)S四极耦合常数为χ_(aa)= -22.6390(23),χ_(bb)= 47.1830(50)和χ_(cc)= -24.5440(50)MHz。

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