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Microextraction of Selected Endocrine Disrupting Phenolic Compounds using Magnetic Chitosan Biopolymer Graphene Oxide Nanocomposite

机译:使用磁性壳聚糖生物聚合物石墨烯氧化物纳米复合材料破坏所选内分泌的微萃取

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摘要

Magnetic chitosan biopolymer, successfully grafted over graphene oxide (MCGO), employed for the efficient extraction of endocrine disrupting phenolic compounds (bisphenol A, 4-tertiary butylphenol and 4-tertiary octylphenol) in single analysis with high performance liquid chromatography. At optimum conditions the adsorption ability calculated for bisphenol A (BPA), 4-tertiary butylphenol (4-tertBP) and 4-tertiary octylphenol (4-tertOP) was 28.98 mgg(-1), 33.22 mgg(-1) and 24.31 mgg(-1), respectively. The results found in the current study showed pseudo second order kinetic and Langmuir adsorption isotherm followed. Suitable extraction solvent was methanol and water in 1:1 ratio and the extraction recoveries calculated for BPA, 4-tertOP and 4-tertBP with relative standard deviations were 92.56% +/- 3.10, 95.23% +/- 4.02 and 95.81% +/- 3.65, respectively. The method was also checked for green chemistry to calculate the eco scale environmental score. The promising adsorbent was also applied effectively to spiked wastewater samples including river water and industrial wastewater.
机译:磁性壳聚糖生物聚合物,成功接枝在石墨烯(MCGO)上,用于高效液相色谱的单一分析中有效地萃取内分泌破坏酚类化合物(双酚A,4-叔丁基苯酚和4-叔丁基苯酚)。在最佳条件下,对双酚A(BPA),4-叔丁基苯酚(4-TertBP)和4-叔辛基苯酚(4-Tertop)计算的吸附能力为28.98MGG(-1),33.22MGG(-1)和24.31 MGG (-1)分别。目前研究中发现的结果显示伪二阶动力学和朗米尔吸附等温线。合适的萃取溶剂是甲醇和水1:1的水,具有相对标准偏差的BPA,4-TERTOP和4-TERTBP的萃取回收率为92.56%+/- 3.10,95.23%+/- 4.02和95.81%+ / - 3.65分别。还检查了绿色化学的方法,以计算Eco规模的环境得分。有希望的吸附剂也有效地应用于包括河水和工业废水的尖刺废水样品。

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