Application of Chemometric Methods in Raman Spectroscopic Studies of Molten Salt System Containing MgCl_2-KCl: Experimental Evidence for Existence of Mg_2Cl_7~(3-) Dimer and Its Raman Spectrum

Sheng Dai; G. M. Begun; J. P. Young; G. Mamantov

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Application of Chemometric Methods in Raman Spectroscopic Studies of Molten Salt System Containing MgCl_2-KCl: Experimental Evidence for Existence of Mg_2Cl_7~(3-) Dimer and Its Raman Spectrum

机译：化学计量学方法在含MgCl_2-KCl熔融盐体系拉曼光谱研究中的应用：Mg_2Cl_7〜（3-）二聚体及其拉曼光谱的实验证据

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Investigation of the Raman spectra of the molten MgCl_2-KCl system by the use of factor analysis indicates that the melt is a two-component system involving equilibrium between MgCl_4~(2-) and Mg_2Cl_7~(3-). The pure Raman spectra corresponding to these two species are recovered from the broad features via a self-modeling method.

机译：通过因子分析研究了熔融的MgCl_2-KCl体系的拉曼光谱，结果表明熔体是一个两组分体系，涉及MgCl_4〜（2-）和Mg_2Cl_7〜（3-）之间的平衡。通过自建模方法从广泛的特征中恢复了与这两个物种相对应的纯拉曼光谱。

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《Journal of Raman Spectroscopy》 |1995年第10期|p.929-932|共4页
作者
Sheng Dai; G. M. Begun; J. P. Young; G. Mamantov;
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Chemical Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6181, USA;

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正文语种 eng
中图分类光学;
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Application of Chemometric Methods in Raman Spectroscopic Studies of Molten Salt System Containing MgCl_2-KCl: Experimental Evidence for Existence of Mg_2Cl_7~(3-) Dimer and Its Raman Spectrum

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