Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis

Patrick D. Parker; Xintong Hou; Vy M. Dong

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Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis

机译：用立体选择性氢化和串联催化减少有机合成中的挑战

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Tandem catalysis enables the rapid construction of complex architectures from simple building blocks. This Perspective shares our interest in combining stereoselective hydrogenation with transformations such as isomerization, oxidation, and epimerization to solve diverse challenges. We highlight the use of tandem hydrogenation for preparing complex natural products from simple prochiral building blocks and present tandem catalysis involving transfer hydrogenation and dynamic kinetic resolution. Finally, we underline recent breakthroughs and opportunities for asymmetric hydrogenation.

机译：串联催化使得能够从简单的构建块快速建造复杂的架构。这种观点份人们对与异构化，氧化和差异等转化相结合的对立体选择性氢化以解决各种挑战的兴趣。我们突出了使用串联氢化来制备来自简单的普罗尔建筑块的复杂天然产物，并存在涉及转移氢化和动态动力学分辨率的串联催化。最后，我们强调了最近的突破和不对称氢化的机会。

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《Journal of the American Chemical Society》 |2021年第18期|6724-6745|共22页
作者
Patrick D. Parker; Xintong Hou; Vy M. Dong;
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作者单位

Department of Chemistry University of California Irvine California 92697 United States;

Department of Chemistry University of California Irvine California 92697 United States;

Department of Chemistry University of California Irvine California 92697 United States;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
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2. Selective deoxygenation of sugar polyols to alpha,omega-diols and other oxygen content reduced materials - a new challenge to homogeneous ionic hydrogenation and hydrogenolysis catalysis [J] . Schlaf M Dalton transactions: An international journal of inorganic chemistry . 2006,第39期

机译：糖多元醇选择性脱氧为α，ω-二醇和其他氧含量降低的材料-均相离子加氢和氢解催化的新挑战
3. Catalysis by Organic Solids. Stereoselective Diels-Alder Reactions Promoted by Microporous Molecular Crystals Having an Extensive Hydrogen-Bonded Network [J] . Ken Endo, Takashi Koike, Tomoya Sawaki Journal of the American Chemical Society . 1997,第18期

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4. The stereoselective synthesis of #alpha#-amino acids by polymer supported phase transfer catalysis [C] . Zhen Wang, Zhengpu Zhang, Yongmei Wang, International conference on biorelated polymers controlled release drugs and reactive polymers . 1997

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5. Rational Design and Synthesis of Inorganic Nanostructures for Tandem Catalysis and CO2 Conversion [D] . Xie, Chenlu. 2018

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6. Stereoselective Organic Reactions in Heterogeneous Semiconductor Photocatalysis [O] . Shigeru Kohtani, Akira Kawashima, Hideto Miyabe 1970

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7. Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality† †This article is part of a ChemComm ‘Catalysis in Organic Synthesis’ web-theme issue showcasing high quality research in organic chemistry. Please see our website (http://www.rsc.org/chemcomm/organicwebtheme2009) to access the other papers in this issue. ‡ ‡Electronic supplementary information (ESI) available: Procedures for the asymmetric autocatalysis in the presence of 1 and 2, the preparation of enantiomers of 1 and 2, and the determination of the enantiomeric purity of 1 and 2. See DOI: 10.1039/b908754k Click here for additional data file. [O] . Kawasaki, Tsuneomi, Shimizu, Masako, Nishiyama, Daisuke, 2009

机译：具有氢同位素手性的陨石氨基酸诱导的不对称自催化† †本文是ChemComm“有机合成催化”网络主题的一部分，该主题展示了有机化学的高质量研究。请访问我们的网站（http://www.rsc.org/chemcomm/organicwebtheme2009）以访问本期的其他论文。 ‡ 可用的电子补充信息（ESI）：在1和2存在下进行不对称自催化的过程，1和2对映体的制备以及1和2对映体纯度的测定。请参见DOI：10.1039 / b908754k 单击此处获取其他数据文件。

Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis

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