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首页> 外文期刊>Materials Letters >Enhanced luminescence from lanthanide complex by silver nanoparticles
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Enhanced luminescence from lanthanide complex by silver nanoparticles

机译:银纳米粒子增强了镧系元素络合物的发光

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摘要

Photoluminescence of europium complex, Eu(III)DPA, where DPA is dipicolinic acid, in the presence of 5 nm-diameter Ag nanoparticles, was studied. Pronounced enhancement of Eu(III) luminescence was observed in the complex solution containing Ag nanoparticle with a concentration below 3.0 x 1013/ml. The dependencies of emission intensity of ~5D_0→~7F_2 and ~5D_0→ 7F_1 transition on the concentration of Ag nanoparticles are quite different, the enhancement of electric dipole transition is stronger than that of magnetic dipole transition. There is no significant change in fluorescence lifetime in enhanced luminescence. The enhancement was attributed to a strong coupling between the radiation transition and surface plasmon resonance.
机译:研究了complex配合物Eu(III)DPA的光致发光,其中DPA是二吡啶甲酸,存在直径为5 nm的Ag纳米颗粒。在包含浓度低于3.0 x 1013 / ml的Ag纳米粒子的复合溶液中观察到Eu(III)发光的明显增强。 〜5D_0→〜7F_2和〜5D_0→7F_1跃迁的发射强度与Ag纳米粒子浓度的相关性相差很大,电偶极跃迁的增强作用比磁偶极跃迁的增强作用强。增强发光的荧光寿命没有显着变化。增强归因于辐射跃迁和表面等离子体共振之间的强耦合。

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