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Effects of seeding and amounts of Y_2O_3: Al_2O_3 additives on grain growth in Si_3N_4 ceramics

机译:Y_2O_3:Al_2O_3添加剂的晶种和添加量对Si_3N_4陶瓷晶粒生长的影响

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摘要

The effect of changing the Y_2O_3:Al_2O_3 additive ratio over grain growth of Si_3_4 materials with and without β-seeds addition is studied. Increasing the amount of Al_2O_3 from 2 to 4 wt.% strongly affects grain growth in non-seeded materials whereas it hardly does in seeded ones. Results suggest that β-seeds addition changes the rate limiting step for the Si_3N_4 grain growth from diffusion to interfacial reaction.
机译:研究了改变Y_2O_3:Al_2O_3添加比例对添加和不添加β种子的Si_3_4材料晶粒生长的影响。 Al_2O_3的含量从2 wt。%增加到4 wt。%会强烈影响非种子材料中的晶粒生长,而几乎不会影响种子材料中的晶粒生长。结果表明,β种子的添加改变了Si_3N_4晶粒生长从扩散到界面反应的限速步骤。

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