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A Rigorous Equation of State for Solids, Liquids, and Gases

机译:固体,液体和气体的严格状态方程

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摘要

In this research report, a rigorous equation of state is derived. Only thermodynamic relationships are used in the derivation, and hence, no restrictive or conditional model is assumed. The advantage of an equation of state that is based on thermodynamic principles is that, by definition, it is applicable to all substances, solid, liquid, or gas. It can, therefore, be used to provide a theoretical insight into other equations of state, notably the van der Waals equation, and as a consistency check for measured thermodynamic data in general. The behavior of the terms in the equation, at and near the critical point, is defined.
机译:在本研究报告中,得出了严格的状态方程。在推导中仅使用热力学关系,因此,不假定任何限制性或条件模型。基于热力学原理的状态方程的优点是,根据定义,它适用于所有物质,包括固体,液体或气体。因此,它可用于提供对其他状态方程(尤其是范德华方程)的理论了解,并通常用作对测得的热力学数据的一致性检查。定义了方程中临界点及其附近的行为。

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