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Chirality in elephant pheromones

机译:大象信息素的手性

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Musth in male elephants is an annual period of heightened sexual activity and aggression that is linked to physical, sexual and social maturation. It is mediated by the release of chemical signals such as the pheromone frontalin, which exists in two chiral forms (molecular mirror images, or enantiomers). Here we show that enantiomers of frontalin are released by Asian elephants in a specific ratio that depends on the animal's age and stage of musth, and that different responses are elicited in male and female conspecifics when the ratio alters. This precise control of communication by molecular chirality offers insight into societal interactions in elephants, and may be useful in implementing new conservation protocols.
机译:雄性大象的肌肉发育是每年性活动和侵略性增强的时期,与身体,性和社会成熟有关。它是由化学信号(如信息素额叶素)的释放介导的,它以两种手性形式(分子镜像或对映异构体)存在。在这里,我们显示了亚洲大象以特定比例释放额叶前列蛋白的对映体,具体比例取决于动物的年龄和发霉阶段,并且当比例改变时,雄性和雌性物种会引发不同的反应。通过分子手性的这种精确的交流控制可以洞察大象中的社会相互作用,并且可能对实施新的保护方案很有用。

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