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Studies on the interaction between 7-(dimethyl amino)-4- (trifluoromethyl)-2H-l-benzopyran-2-one and cadmium sulfide quantum dots

机译:7-(二甲基氨基)-4-(三氟甲基)-2H-1-苯并吡喃-2-酮与硫化镉量子点相互作用的研究

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摘要

Quantum dots (QDs) are well known for their optical properties which differ from those of bulk semiconductors. Herein, we have created an energy transfer platform that combines CdS QDs with a coumarin based dye C485 [7-(dimethyl amino)-4-(trifluoromethyl)-2H-1-benzopyran-2-one]. Spectroscopic studies of energy transfer between the dye donor and CdS QDs as acceptors reveal the occurrence of dynamic quenching. Analysis of the steady-state and time resolved fluorescence measurements of C485 in the presence of CdS QDs infers fluorescence resonance (Forster type) energy transfer (FRET) as responsible for the quenching phenomena. The energy transfer efficiency as well as energy transfer distance for the donor-acceptor pair is calculated using steady-state fluorescence method. Luminescence enhancement of CdS QDs play a critical role in device performance for solar applications and also in the field of biological applications. (C) 2018 Elsevier B.V. All rights reserved.
机译:量子点(QD)的光学特性与体半导体的不同,因此众所周知。在这里,我们创建了一个能量转移平台,将CdS量子点与基于香豆素的染料C485 [7-(二甲基氨基)-4-(三氟甲基)-2H-1-苯并吡喃-2-酮]结合在一起。染料供体和作为受体的CdS QD之间的能量转移的光谱研究表明发生了动态猝灭。在存在CdS QD的情况下对C485的稳态和时间分辨荧光测量结果进行分析,可以推断出荧光共振(福斯特型)能量转移(FRET)是造成猝灭现象的原因。使用稳态荧光方法计算供体-受体对的能量转移效率以及能量转移距离。 CdS QD的发光增强在太阳能应用的器件性能以及生物应用领域中发挥着至关重要的作用。 (C)2018 Elsevier B.V.保留所有权利。

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