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Memory effect in low-density amorphous silicon under pressure

机译:低密度非晶硅在压力下的记忆效应

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摘要

Our investigations on porous Si (π-Si) show that on increase of pressure it undergoes crystalline phase transitions instead of pressure-induced amorphization, as suggested earlier, and the amorphous phase appears only on release of pressure. This amorphous phase, when subjected to higher pressures, transforms reversibly to a higher-coordinated primitive hexagonal phase, showing a kind of memory effect which may be the only example of its kind in the elemental solids. First-principles calculations and thermodynamic arguments help understand these observations.
机译:我们对多孔硅(π-Si)的研究表明,随着压力的增加,它会经历晶相转变,而不是如先前所建议的那样由压力引起的非晶化,并且非晶相仅在压力释放时出现。当受到较高压力时,该非晶相可逆地转变为较高配位的原始六方相,显示出一种记忆效应,可能是其在元素固体中的唯一例子。第一性原理计算和热力学论点有助于理解这些观察结果。

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  • 来源
    《Physical review》 |2011年第11期|p.115202.1-115202.6|共6页
  • 作者单位

    High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India;

    High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India;

    High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India;

    Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India;

    High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    structural transitions in nanoscale materials;

    机译:纳米级材料的结构转变;

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