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Smoothing of ultrathin silver films by transition metal seeding

机译:通过过渡金属种子使超薄银膜光滑

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The nucleation and coalescence of silver islands on coated glass was investigated by in situ measurements of the sheet resistance. Sub-monolayer amounts of niobium and other transition metals were deposited prior to the deposition of silver. It was found that in some cases, the transition metals lead to coalescence of silver at nominally thinner films with smoother topology. The smoothing or roughening effects by the presence of the transition metal can be explained by kinetically limited transition metal islands growth and oxidation, followed by defect-dominated nucleation of silver. (c) 2006 Elsevier Ltd. All rights reserved.
机译:通过表面电阻的原位测量研究了镀膜玻璃上银岛的形核和聚结。在沉积银之前,先沉积亚单层量的铌和其他过渡金属。已经发现,在某些情况下,过渡金属导致银在具有更平滑拓扑的名义上较薄的膜上聚结。过渡金属的存在所引起的平滑或粗糙化效果可以通过动力学上受限的过渡金属岛的生长和氧化来解释,然后以缺陷为主的银成核。 (c)2006 Elsevier Ltd.保留所有权利。

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