Paramagnetic Copper Centers in Ferroelectric Lead Germanate with Halogens

V. A. Vazhenin; A. P. Potapov; M. Yu. Artyomov; A. I. Vylkov

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Paramagnetic Copper Centers in Ferroelectric Lead Germanate with Halogens

机译：铁电含锗锗酸盐中的顺磁铜中心

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The electron paramagnetic resonance spectrum of triclinic bivalent copper centers in copperdoped Pb_5Ge_3O_(11) single crystals has been investigated. The spectrum intensity increases after thermal treatment in a chlorine- or fluorine-containing atmosphere. The parameters of the electron Zeeman, hyperfine, and nuclear quadrupole interactions have been determined. The model of the observed centers has been proposed.

机译：研究了掺铜Pb_5Ge_3O_（11）单晶中三斜晶二价铜中心的电子顺磁共振谱。在含氯或氟的气氛中热处理后，光谱强度增加。已经确定了电子塞曼，超精细和核四极相互作用的参数。已经提出了观测中心的模型。

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《Physics of the solid state》 |2014年第8期|共5页
作者
V. A. Vazhenin; A. P. Potapov; M. Yu. Artyomov; A. I. Vylkov;
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正文语种 eng
中图分类固体物理学;
关键词
Paramagnetic; Copper Centers; Ferroelectric;

机译：顺磁;铜心;铁电;

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专利

1. Paramagnetic Copper Centers in Ferroelectric Lead Germanate with Halogens [J] . V. A. Vazhenin, A. P. Potapov, M. Yu. Artyomov, Physics of the solid state . 2014,第8期

机译：铁电含锗锗酸盐中的顺磁铜中心
2. Effects of the interaction of electron paramagnetic resonance transitions of copper and gadolinium centers in lead germanate single crystals [J] . Vazhenin VA, Guseva VB, Potapov AP, Physics of the solid state . 2006,第8期

机译：锗锗单晶中铜和g中心电子顺磁共振跃迁相互作用的影响
3. Paramagnetic resonance and off-center location of Cu2+ ions in ferroelectric lead germanate [J] . Vazhenin VA, Potapov AP, Guseva VB, Physics of the solid state . 2007,第4期

机译：铁电锗酸铅中Cu2 +离子的顺磁共振和偏心定位
4. Magnetic Resonance and Non-Central Position of Cu~(2+) Ions in Ferroelectric Lead Germanate [C] . Vladimir A. Vazhenin, Alexander P. Potapov, Valentina B. Guseva Asia-Pacific EPR/ESR Symposium . 2006

机译：铁电引线锗锗矿铜〜（2+）离子的磁共振和非中心位置
5. Synthesis and characterization of relaxor-based piezo- and ferroelectric (1-x)lead (zinc(1/3) niobium(2/3)) oxygen(3)-x lead titanate [PZN-PT] and (1-x)lead (magnesium(1/3) niobium(2/3)) oxygen(3)-x lead titanate [PMN-PT]. [D] . Zhang, Lei. 2000

机译：弛豫基压电和铁电（1-x）铅（锌（1/3）铌（2/3））氧（3）-x钛酸铅[PZN-PT]和（1-x）的合成和表征铅（镁（1/3）铌（2/3））氧（3）-x钛酸铅[PMN-PT]。
6. Refined Distances Between Paramagnetic Centers of a Multi-Copper Nitrite Reductase Determined by Pulsed EPR (iDEER) Spectroscopy [O] . Jessica H van Wonderen, Dorota N Kostrz, Christopher Dennison, -1

机译：脉冲EPR（iDEER）光谱测定的多铜亚硝酸盐还原酶顺磁中心之间的精确距离
7. dimer paramagnetic centers in lead germanate crystals doped with iron and halogen (Cl-, Br-, F-) ions [O] . Vazhenin, V. A., Potapov, A. P., Fokin, A. V., 2013

机译：掺杂铁和卤素（Cl-，Br-，F-）离子的锗酸铅晶体中的二聚体顺磁中心
8. Photorefractive Effect in Ferroelectric Lead Germanate. [R] . Krolikowski, W., Cronin-Golomb, M., Chen, B. S. 1990

机译：铁电铅锗酸盐的光折变效应。

Paramagnetic Copper Centers in Ferroelectric Lead Germanate with Halogens

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