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Role of vacancies of a strongly strained crystal in the melting process

机译:高度应变晶体的空位在熔化过程中的作用

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摘要

It has been shown that, apart from classical vacancies formed as a result of the thermal fluctuations, a crystal can contain so-called nonclassical vacancies of nonfluctuation nature. The latter vacancies appear when the temperature exceeds a critical value T_C. The factor responsible for their formation is a mechanical instability of an ideal crystal. The temperature T_C is a second-order phase transition point. The vacancies formed as a result of this phase transition are joined together into small clusters with sizes of the order of several atoms. The above transition makes a substantial contribution to the premelting process observed experimentally.
机译:已经表明,除了由于热波动而形成的经典空位之外,晶体还可以包含具有非波动性质的所谓的非经典空位。当温度超过临界值T_C时,出现后一个空位。导致它们形成的因素是理想晶体的机械不稳定性。温度T_C是二阶相变点。由于该相变而形成的空位被连接在一起,成为具有几个原子数量级的小簇。上述转变对实验观察到的预熔融过程做出了重大贡献。

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