Synthesis and electrochemical properties of Li_(8 - x)Zr_(1 - x)Nb_xO_6 solid solutions

Pantyukhina M.I.; Shchelkanova M.S.; Plaksin S.V.

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Synthesis and electrochemical properties of Li_(8 - x)Zr_(1 - x)Nb_xO_6 solid solutions

机译：Li_（8-x）Zr_（1-x）Nb_xO_6固溶体的合成及电化学性能

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摘要

New lithium-conducting solid solutions based on lithium orthozirconate have been synthesized by mutual doping of the related structures Li_8ZrO_6 and Li_7NbO_6. The main factor determining the increase in the electrical conductivity of the Li_(8 - x)Zr_(1 - x)Nb_xO_6 solid solutions is the formation of lithium vacancies in the tetrahedral and octahedral layers. The practical stability of the Li_(8 - x)Zr_(1 - x)Nb_xO_6 ceramics to metallic lithium has been studied.

机译：通过相互掺杂相关结构Li_8ZrO_6和Li_7NbO_6，合成了基于原锆酸锂的新型导电锂固溶体。决定Li_（8-x）Zr_（1- x）Nb_xO_6固溶体电导率增加的主要因素是在四面体和八面体层中形成锂空位。研究了Li_（8-x）Zr_（1- x）Nb_xO_6陶瓷对金属锂的实际稳定性。

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来源
《Physics of the solid state》 |2013年第4期|共3页
作者
Pantyukhina M.I.; Shchelkanova M.S.; Plaksin S.V.;
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原文格式 PDF
正文语种 eng
中图分类 53.8;
关键词
Synthesis; electrochemical; properties;

机译：合成;电化学;性能;

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1. Synthesis and electrochemical properties of Li_(8 - x)Zr_(1 - x)Nb_xO_6 solid solutions [J] . Pantyukhina M.I., Shchelkanova M.S., Plaksin S.V. Physics of the solid state . 2013,第4期

机译：Li_（8-x）Zr_（1-x）Nb_xO_6固溶体的合成及电化学性能
2. Effects of synthesis conditions on the structural and electrochemical properties of the Li-rich material Li[Li_(0.2)Ni_(0.17)Co_(0.16)Mn_(0.47)]O_2 via the solid-state method [J] . Yanhong Xiang, Zhoulan Yin, Yunhe Zhang, Electrochimica Acta . 2013,第Null期

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Synthesis and electrochemical properties of Li_(8 - x)Zr_(1 - x)Nb_xO_6 solid solutions

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