Copolymerization of functional cyclotrisiloxanes — a reactivity comparison

MAREK CYPRYK; BOGUMILA DELCZYK-OLEJNICZAK

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Copolymerization of functional cyclotrisiloxanes — a reactivity comparison

机译：功能性环三硅氧烷的共聚反应性比较

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Kinetics of controlled simultaneous copolymerization of hexamethylcyclotrisiloxane (D3) with functional cyclotrisiloxanes was studied using n-BuLi in THF as initiator. Trifunctional (MeXSiO)3 (X3), where X = vinyl, trifluoropropyl or chloropropyl group, and monofunctional monomers [(Me2SiO)2MeXSiO] (D2X), where X = cyanopropyl or n-octyl group, were used as monomers. Reactivity ratios for each pair of comonomers were determined and the possibility of synthesis of gradient copolymers by this method is discussed.

机译：以正丁基锂为引发剂，研究了六甲基环三硅氧烷（D3）与官能环三硅氧烷同时受控共聚的动力学。三官能团（MeXSiO）3（X3），其中X =乙烯基，三氟丙基或氯丙基，和单官能团单体[（Me2SiO）2MeXSiO]（D2X），其中X =氰丙基或正辛基，用作单体。确定了每对共聚单体的反应率，并讨论了用这种方法合成梯度共聚物的可能性。

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《Polimery》 |2010年第8期|共9页
作者
MAREK CYPRYK; BOGUMILA DELCZYK-OLEJNICZAK;
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正文语种 eng
中图分类高分子化合物工业（高聚物工业）;
关键词
cyclosiloxanes; polysiloxanes; gradient copolymers; anionic ring opening polymerization; reactivity ratio;

机译：环硅氧烷;聚硅氧烷;梯度共聚物;阴离子开环聚合;反应率;

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1. Copolymerization of functional cyclotrisiloxanes — a reactivity comparison [J] . MAREK CYPRYK, BOGUMILA DELCZYK-OLEJNICZAK Polimery . 2010,第7a8期

机译：功能性环三硅氧烷的共聚反应性比较
2. Copolymerization of N-butyl acrylate with methyl methacrylate and PMMA macromonomers: comparison of reactivity ratios in conventional and atom transfer radical copolymerization [J] . Axel H. E. Muller, Sebastian G. Roos, Krzysztof Maryjaszewski Polymer Preprints . 1999,第2期

机译：丙烯酸N-丁酯与甲基丙烯酸甲酯和PMMA大分子单体的共聚：常规和原子转移自由基共聚反应率的比较
3. Copolymerization of n-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers: Comparison of Reactivity Ratios in Conventional and Atom Transfer Radical Copolymerization [J] . Roos Sebastian G., Muller Axel H.E. Macromolecules . 1999,第25期

机译：丙烯酸正丁酯与甲基丙烯酸甲酯和PMMA大分子单体的共聚合：常规和原子转移自由基共聚合反应比的比较
4. Comparison of potassium-functionalized Cu2ZnSnS4 nanoparticles annealed in different reactive sulfide atmospheres [C] . Sara Engberg, Stela Canulescu, Niels Christian Schj?dt, IEEE World Conference on Photovoltaic Energy Conversion . 2018

机译：钾官能化Cu 2 ZnSNS 4 纳米颗粒在不同反应性硫化物大气中退火
5. New electroactive materials by chemical functionalization of polyethersulfone and copolymerization of reactive monomers [D] . McCarron, Harold Edwin 2003

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6. Organocatalyzed ring-opening copolymerization of α-bromo-γ-butyrolactone with ε-caprolactone for the synthesis of functional aliphatic polyesters – pre-polymers for graft copolymerization [O] . Chen Gao, Chi-Hui Tsou, Chun-Yan Zeng, 2018

机译：α-溴-γ-丁内酯与ε-己内酯的有机催化开环共聚反应以合成功能性脂肪族聚酯-接枝共聚的预聚物
7. Precise Synthesis of Side-Chain-Functionalized Linear Polysiloxanes by Organocatalytic Ring-Opening Polymerization of Monofunctional Cyclotrisiloxanes [O] . -1

机译：单官能环氧硅氧烷单官能开环聚合精确合成侧链官能化直链聚硅氧烷

Copolymerization of functional cyclotrisiloxanes — a reactivity comparison

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