The effect of tri(1-chloro-3-etoxy-propane-2-ol) borate on the properties of rigid polyurethane-polyisocyanurate foams

Boguslaw Czuprynski; Joanna Paciorek-Sadowska; Joanna Liszkowska

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The effect of tri(1-chloro-3-etoxy-propane-2-ol) borate on the properties of rigid polyurethane-polyisocyanurate foams

机译：硼酸三（1-氯-3-甲氧基-丙烷-2-醇）对硬质聚氨酯-聚异氰脲酸酯泡沫塑料性能的影响

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Tri(1-chloro-3-etoxy-propane-2-ol) borate (I) was obtained by reaction of tri(hydroxyethyl)borate and epichlorohydrin.Reaction product was applied as fire retardant forpreparation of rigid polyuethane-polyisocyanurate foams.As the (I) content was increased from 0.1 to 0.4 of the chemical equivalent,the compressive strength,oxygenindex,residue after combustion and content of closed cells rose but brittleness,softening point and water absorption decreased.however,(I) presence does not influence explicitly on the foam apparent density.The results of our studies showed that chloroboroorganic compound [ChBOC,(I)] is generally useful as an additive to improve the properties of rigid PUR-PIR foams.

机译：通过三（羟乙基）硼酸酯与环氧氯丙烷反应制得三（1-氯-3-环氧乙烷-丙烷-2-醇）硼酸酯（I），该反应产物用作阻燃剂，用于制备硬质聚氨酯-聚异氰脲酸酯泡沫。（I）的含量从化学当量的0.1增加到0.4，燃烧后的抗压强度，氧指数，残余物和闭孔的含量增加，但脆性，软化点和吸水率下降。我们的研究结果表明，氯硼有机化合物[ChBOC，（I）]通常可作为添加剂来改善硬质PUR-PIR泡沫的性能。

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《Polimery》 |2002年第10期|共3页
作者
Boguslaw Czuprynski; Joanna Paciorek-Sadowska; Joanna Liszkowska;
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中图分类高分子化合物工业（高聚物工业）;
关键词
rigid PUR-PIR foams; fire retardancy; tri(1-chloro-3-etoxy-propane-2-ol) borate; properties of foams;

机译：硬质PUR-PIR泡沫;阻燃性;三（1-氯-3-甲氧基-丙烷-2-醇）硼酸酯;泡沫的性能;

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1. The effect of tri(1-chloro-3-etoxy-propane-2-ol) borate on the properties of rigid polyurethane-polyisocyanurate foams [J] . Boguslaw Czuprynski, Joanna Paciorek-Sadowska, Joanna Liszkowska Polimery . 2002,第10期

机译：硼酸三（1-氯-3-甲氧基-丙烷-2-醇）对硬质聚氨酯-聚异氰脲酸酯泡沫塑料性能的影响
2. Studies on Effect of Tri(2-hydroxypropyl), Tri(2-hydroxybutyl) and Tri(hydroxythiodiethylene) Borates on Thermal and Heat Properties of Rigid Polyurethane-Polyisocyanurate Foams [J] . CZUPRYNSKI Boguslaw, PACIOREK-SADOWSKA Joanna, LISZKOWSKA Joanna 中国化学（英文版） . 2006,第012期

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The effect of tri(1-chloro-3-etoxy-propane-2-ol) borate on the properties of rigid polyurethane-polyisocyanurate foams

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