SYNTHESIS AND SPECTROSCOPIC STUDIES OF MANGANESE PORPHYRIN-THIOLATE COMPLEXES

Mu LJ.; Zhou YQ.; Shen PW.; Huang JS.

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >SYNTHESIS AND SPECTROSCOPIC STUDIES OF MANGANESE PORPHYRIN-THIOLATE COMPLEXES

【24h】

SYNTHESIS AND SPECTROSCOPIC STUDIES OF MANGANESE PORPHYRIN-THIOLATE COMPLEXES

机译：锰卟啉-硫醇盐配合物的合成与光谱研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The synthesis and spectroscopic characterization of four manganese(III) porphyrin thiolates are reported. The investigated compounds are represented by (TPP)Mn(SR), where TPP is the dianion of tetraphenylporhyrin and R is C6H5, C6H4(p-NO2), Et2NCS and C4H8NCS. Each complex was characterized by UV-vis and H-1 NMR spectroscopy. The effects of axial ligands on the UV-vis spectra of synthesized manganese porphyrin complexes is discussed and proton isotropic shifts are shown to be predominantly contact in origin, reflecting extensive porphyrin-to-metal pi bonding. (C) 1997 Elsevier Science Ltd. [References: 25]

机译：报道了四种锰（III）卟啉硫醇盐的合成和光谱表征。研究的化合物以（TPP）Mn（SR）表示，其中TPP是四苯基卟啉的二价阴离子，R是C6H5，C6H4（p-NO2），Et2NCS和C4H8NCS。通过UV-vis和H-1 NMR光谱表征每种复合物。讨论了轴向配体对合成锰卟啉配合物的紫外-可见光谱的影响，并且质子各向同性位移显示出主要是起源接触，反映了广泛的卟啉-金属pi键。（C）1997 Elsevier Science Ltd. [参考：25]

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第16期|共4页
作者
Mu LJ.; Zhou YQ.; Shen PW.; Huang JS.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词
Manganese porphyrin thiolate; Synthesis; Uv-vis; Nmr; Metalloporphyrins; Cytochrome-p-450; Reactivity; Cleavage; Models; State;

机译：硫酸锰卟啉;合成;紫外可见;Nmr;金属卟啉;细胞色素p-450;反应性;裂解;模型;状态;

相似文献

外文文献
中文文献
专利

1. SYNTHESIS AND SPECTROSCOPIC STUDIES OF MANGANESE PORPHYRIN-THIOLATE COMPLEXES [J] . Mu LJ., Zhou YQ., Shen PW., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第16期

机译：锰卟啉-硫醇盐配合物的合成与光谱研究
2. Divalent manganese, cobalt and nickel chloride complexes with neutral N-2- and N-3-based ligands derived from 2-pyridinecarbaldehyde: Synthesis, structural features and spectroscopic studies [J] . Buvaylo Elena A., Melnyk Andrii K., Trachevsky Vladimir V., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2016,第Null期

机译：带有2-吡啶甲醛的中性N-2-和N-3-配体的二价锰，钴和氯化镍配合物的合成，结构特征和光谱研究
3. Synthesis, structure, spectroscopic and DFT studies of zinc(II) and manganese( II) complexes of 2-pyridine carboxaldehyde-N-methyl-N-2-pyridyl hydrazone [J] . Ali Basem F., Judeh Zaher, Ayub Khurshid Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2015,第Null期

机译：2-吡啶甲醛-N-甲基-N-2-吡啶基hydr的锌（II）和锰（II）配合物的合成，结构，光谱和DFT研究
4. Pd(Ⅱ), Pt(Ⅱ) and Cu(Ⅱ) Complexes of N,N'-bis(l-methoxycarbonylethyl)ethanedithioamide Synthesis and Spectroscopic Studies [C] . Liliana Stoicescu, Maria Negoiu, Rodica Georgescu, 12th Romanian International Conference on Chemistry and Chemical Engineering, Sep 13-15, 2001, Bucharest, Romania . 2001

机译：N，N'-双（1-甲氧基羰基乙基）乙烷二硫代酰胺的Pd（Ⅱ），Pt（Ⅱ）和Cu（Ⅱ）配合物的合成及光谱研究
5. Synthesis, characterization, and reactivity of titanocene cyclic organohydroborates; synthesis, spectroscopic studies, and structures of lanthanide(II)-cobalt carbonyl complexes. [D] . Plecnik, Christine E. 2003

机译：钛茂环有机硼酸酯的合成，表征和反应性；镧（II）-羰基钴配合物的合成，光谱研究和结构。
6. 12-Benzenedithiol and Toluene-34-dithiol Arsenic(III) Complexes—Synthesis Structure Spectroscopic Characterization and Toxicological Studies [O] . Monika Lyczko, Krzysztof Lyczko, Agnieszka Majkowska-Pilip, 2019

机译：12-苯二硫醇和甲苯-34-二硫醇砷（III）配合物的合成结构光谱表征和毒理学研究
7. Synthesis, Spectroscopic and Antimicrobial Studies on Copper(II), Cobalt(II), Nickel(II) and Manganese(II) Complexes of N-(2-Ethylphenyl) N'-Picolinoyl Hydrazine [O] . Netra Pal Singh, Jagvir Singh 2013

机译：铜（II），钴（II），镍（II），N-（2-乙基苯基）N'-PICOLINOYL肼的锰（II）复合物的合成，光谱和抗微生物研究

SYNTHESIS AND SPECTROSCOPIC STUDIES OF MANGANESE PORPHYRIN-THIOLATE COMPLEXES

摘要

著录项

相似文献

相关主题

期刊订阅