CRYSTAL STRUCTURE AND PROPERTIES OF NEODYMIUM COMPLEX WITH HEXAAZACYCLOOCTADECANE LIGAND

Bu XH.; Zhang RH.; Wang HG.; Yao XK.; Lu SL.

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CRYSTAL STRUCTURE AND PROPERTIES OF NEODYMIUM COMPLEX WITH HEXAAZACYCLOOCTADECANE LIGAND

机译：十六碳环十二烷配体钕络合物的晶体结构和性能

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The neodymium complex with hexaazacyclooctadecane ([18]aneN(6)) has been obtained as a single crystal by the reaction of neodymium nitrate and macrocycle ligand in methanol solution. The crystal structure of the complex [Nd([18]aneN(6)) (NO3)(3)] was determined by X-ray diffraction. The neodymium centre is 10-coordinate with the coordination polyhedron being an irregular capped square-antiprism. The absorption spectrum of the complex was measured and the intensities of f-f transitions were analyzed according to the Judd-Ofelt theory. (C) 1997 Elsevier Science Ltd. [References: 16]

机译：具有六氮杂环十八烷（[18] aneN（6））的钕配合物已通过硝酸钕与大环配体在甲醇溶液中的反应获得为单晶。配合物[Nd（[18] aneN（6））（NO3）（3）]的晶体结构通过X射线衍射测定。钕中心为10坐标，配位多面体为不规则的加盖方形反棱镜。根据Judd-Ofelt理论，测量了络合物的吸收光谱，并分析了f-f跃迁的强度。（C）1997 Elsevier Science Ltd. [引用：16]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |1997年第19期|共5页
作者
Bu XH.; Zhang RH.; Wang HG.; Yao XK.; Lu SL.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Crystal structure; Neodymium complex; Hexaazacyclooctadecane; Properties; Lanthanides;

机译：晶体结构;钕配合物;六氮杂环十八烷;性质;镧系元素;

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1. CRYSTAL STRUCTURE AND PROPERTIES OF NEODYMIUM COMPLEX WITH HEXAAZACYCLOOCTADECANE LIGAND [J] . Bu XH., Zhang RH., Wang HG., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1997,第19期

机译：十六碳环十二烷配体钕络合物的晶体结构和性能
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CRYSTAL STRUCTURE AND PROPERTIES OF NEODYMIUM COMPLEX WITH HEXAAZACYCLOOCTADECANE LIGAND

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