Network diversity and supramolecular isomerism in copper(II)/1,2-bis(4- pyridyl)ethane coordination polymers

Lazarou K.N.; Psycharis V.; Terzis A.; Raptopoulou C.P.

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Network diversity and supramolecular isomerism in copper(II)/1,2-bis(4- pyridyl)ethane coordination polymers

机译：铜（II）/ 1,2-双（4-吡啶基）乙烷配位聚合物中的网络多样性和超分子异构

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Reactions of copper(II) sources with 1,2-bis(4-pyridyl)ethane (bpe) yielded metal-organic networks with diverse topologies and dimensionalities. Compounds [Cu(bpe)_2(dmf)_2]_n(ClO_4) _(2n)·2ndmf (1·2ndmf), [Cu(bpe) _2(dmf)_2]_n(ClO_4)_(2n)·3.5ndmf (2·3.5ndmf), [Cu(bpe)_2(NO _3)_2]_n·2nH2O (4·2nH_2O) and [Cu_2(bpe)(O_2CMe) _4]_n·0.7nH_2O (5·0.7nH _2O) have been isolated by altering the copper(II) source, the reaction solvent and the crystallization process. Compounds 1·2ndmf and 2·3.5ndmf consist of cationic [Cu(bpe)_2(dmf)_2] ~(2+) repeating units assembled to 1D and 2D (4,4) networks, respectively, and represent supramolecular isomers due to the conformational isomerism of the bridging bpe molecules. Compound 4·2nH_2O consists of neutral mononuclear [Cu(dpe)_2(NO_3) _2] repeating units assembled to inclined interpenetrating (4,4) sheets describing an overall entanglement that is 3D in nature, and compound 5·0.7nH_2O consists of neutral dinuclear repeating units assembled to cross-linked 1D chains.

机译：铜（II）源与1,2-双（4-吡啶基）乙烷（bpe）的反应产生了具有多种拓扑结构和尺寸的金属有机网络。化合物[Cu（bpe）_2（dmf）_2] _n（ClO_4）_（2n）·2ndmf（1·2ndmf），[Cu（bpe）_2（dmf）_2] _n（ClO_4）_（2n）·3.5ndmf （2·3.5ndmf），[Cu（bpe）_2（NO _3）_2] _n·2nH2O（4·2nH_2O）和[Cu_2（bpe）（O_2CMe）_4] _n·0.7nH_2O（5·0.7nH _2O）具有通过改变铜（II）的来源，反应溶剂和结晶过程可以分离出铜。化合物1·2ndmf和2·3.5ndmf由分别组装成1D和2D（4,4）网络的阳离子[Cu（bpe）_2（dmf）_2]〜（2+）重复单元组成，它们代表超分子异构体桥接bpe分子的构象异构现象。化合物4·2nH_2O由中性单核[Cu（dpe）_2（NO_3）_2]重复单元组成，这些单元组装成互穿的（4,4）倾斜薄片，描述了3D的整体缠结，化合物5·0.7nH_2O由中性组成双核重复单元组装成交联的一维链。

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2011年第6期|共8页
作者
Lazarou K.N.; Psycharis V.; Terzis A.; Raptopoulou C.P.;
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正文语种 eng
中图分类无机化学;
关键词
1; 2-Bis(4-pyridyl)ethane; Coordination polymers; Copper(II) complexes; Supramolecular isomerism;

机译：1;2-双（4-吡啶基）乙烷;配位聚合物;铜（II）配合物;超分子异构;

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1. Network diversity and supramolecular isomerism in copper(II)/1,2-bis(4- pyridyl)ethane coordination polymers [J] . Lazarou K.N., Psycharis V., Terzis A., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2011,第6期

机译：铜（II）/ 1,2-双（4-吡啶基）乙烷配位聚合物中的网络多样性和超分子异构
2. Supramolecular architectures and magnetic behavior of coordination polymers from copper(II) carboxylates and 1,2-bis(4-pyridyl)ethane as a flexible bridging ligand [J] . Carballo R, Covelo B, El Fallah MS, Crystal growth & design . 2007,第6期

机译：羧酸铜（II）和1,2-双（4-吡啶基）乙烷作为柔性桥联配体的配位聚合物的超分子结构和磁性行为
3. Novel lanthanide(III) coordination networks based on 1,2-bis(4-pyridyl)ethane-N,N'-dioxide and tran-1,2-bis(4-pyridyl)ethene-N,N'-dioxide [J] . Wen-Jie Lu, Lin-Ping Zhang, Hai-Bin Song, New Journal of Chemistry . 2002,第6期

机译：基于1,2-双（4-吡啶基）乙烷-N，N'-二氧化物和反式-1,2-双（4-吡啶基）乙烯-N，N'-二氧化物的新型镧系元素（III）配位网络
4. Assembled Iron Complexes Bridged with Bipyridine or 1,2-Bis(4-pyridyl)ethane as Molecular Zeolite [C] . Satoru Nakashima, Takaki Morita, Tsutomu Okuda International Symposium on the Industrial Applications of the Mössbauer Effect . 2005

机译：将桥接的铁络合物组装为与二吡啶或1,2-双（4-吡啶基）乙烷作为分子沸石
5. Studies into selective fluorination and the coordination chemistry of alkyl iodides and the ligands meso and racemic 1,2-bis(phenylphosphine-oxide)ethane. [D] . Horvath, Michael John. 1994

机译：研究烷基碘与配体的内消旋和外消旋1,2-双（苯基膦氧化物）乙烷的选择性氟化和配位化学。
6. Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate [O] . Qiaozhen Sun, Tao Xiao, Ping Chen, 2016

机译：溶解的双[μ-1,2-二苯基-N，N'-双（二-2-吡啶基亚甲基氨基）乙烷-1,2-二亚胺]分散液（I）双（六氟磷酸）乙腈
7. Supramolecular Architectures and Magnetic Behavior of Coordination Polymers from Copper(II) Carboxylates and 1,2-Bis(4-pyridyl)ethane as a Flexible Bridging Ligand [O] . -1

机译：来自铜（II）羧酸铜（II）羧酸盐和1,2-双（4-吡啶基）乙烷作为柔性桥接配体的协调聚合物的超分子架构和磁性。

Network diversity and supramolecular isomerism in copper(II)/1,2-bis(4- pyridyl)ethane coordination polymers

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